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| Home > Publications database > Directed Immobilization of Janus-AuNP in Heterometallic Nanogaps: a Key Step Toward Integration of Functional Molecular Units in Nanoelectronics > print |
| 001 | 172802 | ||
| 005 | 20210129214517.0 | ||
| 024 | 7 | _ | |a 10.1021/jp5085179 |2 doi |
| 024 | 7 | _ | |a 1932-7447 |2 ISSN |
| 024 | 7 | _ | |a 1932-7455 |2 ISSN |
| 024 | 7 | _ | |a WOS:000345474000082 |2 WOS |
| 037 | _ | _ | |a FZJ-2014-06243 |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Babajani, Ninet |0 P:(DE-Juel1)142224 |b 0 |e Corresponding Author |u fzj |
| 245 | _ | _ | |a Directed Immobilization of Janus-AuNP in Heterometallic Nanogaps: a Key Step Toward Integration of Functional Molecular Units in Nanoelectronics |
| 260 | _ | _ | |a Washington, DC |c 2014 |b Soc. |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1417007105_3097 |2 PUB:(DE-HGF) |
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| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
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| 336 | 7 | _ | |a article |2 DRIVER |
| 520 | _ | _ | |a Forming reliable and reproducible molecule−nanoelectrodecontacts is one of the key issues for the implementation of nanoparticles asfunctional units into nanoscale devices. Utilizing heterometallic electrodes andJanus-type nanoparticles equipped with molecules allowing selective bindingto a distinct electrode material represents a promising approach to achievethis goal. Here, the directed immobilization of individual Janus-type goldnanoparticles (AuNP) between heterometallic electrodes leading to theformation of asymmetric contacts in a highly controllable way is presented.The Janus-AuNP are stabilized by two types of ligands with different terminalgroups on opposite hemispheres. The heterometallic nanoelectrode gaps areformed by electron beam lithography in combination with a self-alignmentprocedure and are adjusted to the size of the Janus-AuNP. Thus, by choosingadequate molecular end group/metal combinations, the immobilizationdirection of the Janus-AuNP is highly controllable. These results demonstratethe striking potential of this approach for the building-up of novel nanoscale organic/inorganic hybrid architectures. |
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| 700 | 1 | _ | |a Kaulen, Corinna |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Homberger, Melanie |0 P:(DE-HGF)0 |b 2 |
| 700 | 1 | _ | |a Mennicken, Max |0 P:(DE-Juel1)136859 |b 3 |u fzj |
| 700 | 1 | _ | |a Waser, Rainer |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Simon, Ulrich |0 P:(DE-HGF)0 |b 5 |
| 700 | 1 | _ | |a Karthäuser, Silvia |0 P:(DE-Juel1)130751 |b 6 |u fzj |
| 773 | _ | _ | |a 10.1021/jp5085179 |g Vol. 118, no. 46, p. 27142 - 27149 |0 PERI:(DE-600)2256522-X |n 46 |p 27142 - 27149 |t The @journal of physical chemistry |v 118 |y 2014 |x 1932-7455 |
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