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000172889 1001_ $$0P:(DE-Juel1)144500$$aKlobes, B.$$b0$$eCorresponding Author
000172889 245__ $$aHyperfine interactions in and lattice parameters of pyrochlore and defect fluorite ${\left({\mathrm{Eu}}_{1-x}{\mathrm{Nd}}_{x}\right)}_{2}{\mathrm{Zr}}_{m2}{\mathrm{O}}_{7}$
000172889 260__ $$aNew York, NY [u.a.]$$bElsevier$$c2015
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000172889 520__ $$aPyrochlore and defect fluorite (Eu1−xNdx)2Zr2O7 compounds (x = 0, 0.5 and 0.75) synthesized by a wet chemicalapproach were investigated using temperature dependent high energy X-ray diffraction as well as 151Eu Mössbauerspectroscopy. Diffraction data reveals an increase in lattice parameter with increasing Nd content, an increase thatis disproportionally large between x = 0.5 and 0.75. The 151Eu Mössbauer spectral parameters, i.e. isomer shift andquadrupole splitting, fall in separate regions for pyrochlore and defect fluorite type compounds. Between 80 - 350 K,the impact of the order-disorder, i.e. pyrochlore to defect fluorite, transition on isomer shift and quadrupole splittingis found to exceed the one due to lattice expansion.
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000172889 7001_ $$0P:(DE-Juel1)142526$$aFinkeldei, S.$$b1
000172889 7001_ $$0P:(DE-Juel1)157665$$aRöhrig, Wilbert$$b2
000172889 7001_ $$0P:(DE-Juel1)130324$$aBosbach, D.$$b3
000172889 7001_ $$0P:(DE-HGF)0$$aHermann, R. P.$$b4
000172889 773__ $$0PERI:(DE-600)1491914-x$$a10.1016/j.jpcs.2014.11.011$$gp. S0022369714002844$$p43–48$$tJournal of physics and chemistry of solids$$v79$$x0022-3697$$y2015
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