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@ARTICLE{Klobes:172889,
      author       = {Klobes, B. and Finkeldei, S. and Röhrig, Wilbert and
                      Bosbach, D. and Hermann, R. P.},
      title        = {{H}yperfine interactions in and lattice parameters of
                      pyrochlore and defect fluorite
                      ${\left({\mathrm{{E}u}}_{1-x}{\mathrm{{N}d}}_{x}\right)}_{2}{\mathrm{{Z}r}}_{m2}{\mathrm{{O}}}_{7}$},
      journal      = {Journal of physics and chemistry of solids},
      volume       = {79},
      issn         = {0022-3697},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2014-06320},
      pages        = {43–48},
      year         = {2015},
      abstract     = {Pyrochlore and defect fluorite (Eu1−xNdx)2Zr2O7 compounds
                      (x = 0, 0.5 and 0.75) synthesized by a wet chemicalapproach
                      were investigated using temperature dependent high energy
                      X-ray diffraction as well as 151Eu Mössbauerspectroscopy.
                      Diffraction data reveals an increase in lattice parameter
                      with increasing Nd content, an increase thatis
                      disproportionally large between x = 0.5 and 0.75. The 151Eu
                      Mössbauer spectral parameters, i.e. isomer shift
                      andquadrupole splitting, fall in separate regions for
                      pyrochlore and defect fluorite type compounds. Between 80 -
                      350 K,the impact of the order-disorder, i.e. pyrochlore to
                      defect fluorite, transition on isomer shift and quadrupole
                      splittingis found to exceed the one due to lattice
                      expansion.},
      cin          = {IEK-6 / JCNS-2 / JARA-FIT / PGI-4},
      ddc          = {530},
      cid          = {I:(DE-Juel1)IEK-6-20101013 / I:(DE-Juel1)JCNS-2-20110106 /
                      $I:(DE-82)080009_20140620$ / I:(DE-Juel1)PGI-4-20110106},
      pnm          = {161 - Nuclear Waste Management (POF3-161)},
      pid          = {G:(DE-HGF)POF3-161},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000349505000005},
      doi          = {10.1016/j.jpcs.2014.11.011},
      url          = {https://juser.fz-juelich.de/record/172889},
}