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024 | 7 | _ | |2 doi |a 10.1016/j.jpcs.2014.11.011 |
024 | 7 | _ | |2 ISSN |a 0022-3697 |
024 | 7 | _ | |2 ISSN |a 0369-8726 |
024 | 7 | _ | |2 ISSN |a 1879-2553 |
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100 | 1 | _ | |0 P:(DE-Juel1)144500 |a Klobes, B. |b 0 |e Corresponding Author |
245 | _ | _ | |a Hyperfine interactions in and lattice parameters of pyrochlore and defect fluorite ${\left({\mathrm{Eu}}_{1-x}{\mathrm{Nd}}_{x}\right)}_{2}{\mathrm{Zr}}_{m2}{\mathrm{O}}_{7}$ |
260 | _ | _ | |a New York, NY [u.a.] |b Elsevier |c 2015 |
336 | 7 | _ | |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |a Journal Article |b journal |m journal |s 1429109525_26846 |
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336 | 7 | _ | |2 DRIVER |a article |
520 | _ | _ | |a Pyrochlore and defect fluorite (Eu1−xNdx)2Zr2O7 compounds (x = 0, 0.5 and 0.75) synthesized by a wet chemicalapproach were investigated using temperature dependent high energy X-ray diffraction as well as 151Eu Mössbauerspectroscopy. Diffraction data reveals an increase in lattice parameter with increasing Nd content, an increase thatis disproportionally large between x = 0.5 and 0.75. The 151Eu Mössbauer spectral parameters, i.e. isomer shift andquadrupole splitting, fall in separate regions for pyrochlore and defect fluorite type compounds. Between 80 - 350 K,the impact of the order-disorder, i.e. pyrochlore to defect fluorite, transition on isomer shift and quadrupole splittingis found to exceed the one due to lattice expansion. |
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700 | 1 | _ | |0 P:(DE-Juel1)142526 |a Finkeldei, S. |b 1 |
700 | 1 | _ | |0 P:(DE-Juel1)157665 |a Röhrig, Wilbert |b 2 |
700 | 1 | _ | |0 P:(DE-Juel1)130324 |a Bosbach, D. |b 3 |
700 | 1 | _ | |0 P:(DE-HGF)0 |a Hermann, R. P. |b 4 |
773 | _ | _ | |0 PERI:(DE-600)1491914-x |a 10.1016/j.jpcs.2014.11.011 |g p. S0022369714002844 |p 43–48 |t Journal of physics and chemistry of solids |v 79 |x 0022-3697 |y 2015 |
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