Home > Publications database > Structural invariance upon antiferromagnetic ordering in geometrically frustrated swedenborgite, CaBaCo 2 Fe 2 O 7 > print

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005     20240529111754.0
024 7 _ |2 doi
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082 _ _ |a 540
100 1 _ |a Rosén, E.
|b 0
245 _ _ |a Structural invariance upon antiferromagnetic ordering in geometrically frustrated swedenborgite, CaBaCo 2 Fe 2 O 7
260 _ _ |a Copenhagen
|b Munksgaard
|c 2014
336 7 _ |a Journal Article
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520 _ _ |a Centimetre-sized single crystals of high-quality CaBaCo2Fe2O7 were synthesized by the optical floating zone technique. The metal-to-metal stoichiometry and oxygen content were confirmed by spectroscopy and thermal reduction experiments. The hexagonal symmetry P63mc (No. 186) well describes the powder X-ray and neutron diffraction as well as single-crystal neutron diffraction at all measured temperatures. This symmetry is also consistent with optical second harmonic generation data obtained between 10 and 295 K. However, a satisfactory structure description from single-crystal neutron diffraction data needs an oxygen split position. Specific heat, magnetic susceptibility and powder neutron diffraction data indicate a magnetic phase transition at TN = 159 K to an antiferromagnetic ground state, but with a persisting hexagonal symmetry and intrinsic geometric frustration.
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