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000017435 0247_ $$2DOI$$a10.1021/es200224c
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000017435 084__ $$2WoS$$aEngineering, Environmental
000017435 084__ $$2WoS$$aEnvironmental Sciences
000017435 1001_ $$0P:(DE-HGF)0$$aShan, J.$$b0
000017435 245__ $$aIsomer-Specific Degradation of Branched and Linear 4-Nonylphenol Isomers in an Oxic Soil
000017435 260__ $$aColumbus, Ohio$$bAmerican Chemical Society$$c2011
000017435 300__ $$a8283 - 8289
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000017435 440_0 $$01865$$aEnvironmental Science and Technology$$v45$$x0013-936X$$y19
000017435 500__ $$3POF3_Assignment on 2016-02-29
000017435 500__ $$aThis study was supported by the National Science Foundation of China (grant nos. 20777033, 20977043, and 41030746).
000017435 520__ $$aUsing (14)C- and (13)C-ring-labeling, degradation of five p-nonylphenol (4-NP) isomers including four branched (4-NP(38), 4-NP(65), 4-NP(111), and 4-NP(112)) and one linear (4-NP(1)) isomers in a rice paddy soil was studied under oxic conditions. Degradation followed an availability-adjusted first-order kinetics with the decreasing order of half-life 4-NP(111) (10.3 days) > 4-NP(112) (8.4 days) > 4-NP(65) (5.8 days) > 4-NP(38) (2.1 days) > 4-NP(1) (1.4 days), which is in agreement with the order of their reported estrogenicities. One metabolite of 4-NP(111) with less polarity than the parent compound occurred rapidly and remained stable in the soil. At the end of incubation (58 days), bound residues of 4-NP(111) amounted to 54% of the initially applied radioactivity and resided almost exclusively in the humin fraction of soil organic matter, in which chemically humin-bound residues increased over incubation. Our results indicate an increase of specific estrogenicity of the remaining 4-NPs in soil as a result of the isomer-specific degradation and therefore underline the importance of understanding the individual fate (including degradation, metabolism, and bound-residue formation) of isomers for risk assessment of 4-NPs in soil. 4-NP(1) should not be used as a representative of 4-NPs for studies on their environmental behavior.
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000017435 650_2 $$2MeSH$$aCarbon Isotopes
000017435 650_2 $$2MeSH$$aChemical Fractionation
000017435 650_2 $$2MeSH$$aEnvironment
000017435 650_2 $$2MeSH$$aHumic Substances: analysis
000017435 650_2 $$2MeSH$$aIsomerism
000017435 650_2 $$2MeSH$$aKinetics
000017435 650_2 $$2MeSH$$aMinerals: chemistry
000017435 650_2 $$2MeSH$$aOryza sativa
000017435 650_2 $$2MeSH$$aOxygen: chemistry
000017435 650_2 $$2MeSH$$aPhenols: chemistry
000017435 650_2 $$2MeSH$$aRadioactivity
000017435 650_2 $$2MeSH$$aSoil: chemistry
000017435 650_7 $$00$$2NLM Chemicals$$aCarbon Isotopes
000017435 650_7 $$00$$2NLM Chemicals$$aHumic Substances
000017435 650_7 $$00$$2NLM Chemicals$$aMinerals
000017435 650_7 $$00$$2NLM Chemicals$$aPhenols
000017435 650_7 $$00$$2NLM Chemicals$$aSoil
000017435 650_7 $$0104-40-5$$2NLM Chemicals$$a4-nonylphenol
000017435 650_7 $$07782-44-7$$2NLM Chemicals$$aOxygen
000017435 650_7 $$2WoSType$$aJ
000017435 7001_ $$0P:(DE-HGF)0$$aJiang, B.Q.$$b1
000017435 7001_ $$0P:(DE-HGF)0$$aYu, B.$$b2
000017435 7001_ $$0P:(DE-Juel1)VDB102196$$aLi, CL.$$b3$$uFZJ
000017435 7001_ $$0P:(DE-HGF)0$$aSun, YY.$$b4
000017435 7001_ $$0P:(DE-HGF)0$$aGuo, HY.$$b5
000017435 7001_ $$0P:(DE-HGF)0$$aWu, JC.$$b6
000017435 7001_ $$0P:(DE-Juel1)129484$$aKlumpp, E.$$b7$$uFZJ
000017435 7001_ $$0P:(DE-HGF)0$$aSchaeffer, A.$$b8
000017435 7001_ $$0P:(DE-HGF)0$$aJi, R.$$b9
000017435 773__ $$0PERI:(DE-600)1465132-4$$a10.1021/es200224c$$gVol. 45, p. 8283 - 8289$$p8283 - 8289$$q45<8283 - 8289$$tEnvironmental Science & Technology$$v45$$x0013-936X$$y2011
000017435 8567_ $$uhttp://dx.doi.org/10.1021/es200224c
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