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|a pmid:21823570
024 7 _ |2 DOI
|a 10.1021/es200224c
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|a WOS:000295245600047
024 7 _ |2 ISSN
|a 0013-936X
024 7 _ |2 ISSN
|a 1520-5851
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037 _ _ |a PreJuSER-17435
041 _ _ |a eng
082 _ _ |a 050
084 _ _ |2 WoS
|a Engineering, Environmental
084 _ _ |2 WoS
|a Environmental Sciences
100 1 _ |0 P:(DE-HGF)0
|a Shan, J.
|b 0
245 _ _ |a Isomer-Specific Degradation of Branched and Linear 4-Nonylphenol Isomers in an Oxic Soil
260 _ _ |a Columbus, Ohio
|b American Chemical Society
|c 2011
300 _ _ |a 8283 - 8289
336 7 _ |a Journal Article
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336 7 _ |a article
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440 _ 0 |0 1865
|a Environmental Science and Technology
|v 45
|x 0013-936X
|y 19
500 _ _ |3 POF3_Assignment on 2016-02-29
500 _ _ |a This study was supported by the National Science Foundation of China (grant nos. 20777033, 20977043, and 41030746).
520 _ _ |a Using (14)C- and (13)C-ring-labeling, degradation of five p-nonylphenol (4-NP) isomers including four branched (4-NP(38), 4-NP(65), 4-NP(111), and 4-NP(112)) and one linear (4-NP(1)) isomers in a rice paddy soil was studied under oxic conditions. Degradation followed an availability-adjusted first-order kinetics with the decreasing order of half-life 4-NP(111) (10.3 days) > 4-NP(112) (8.4 days) > 4-NP(65) (5.8 days) > 4-NP(38) (2.1 days) > 4-NP(1) (1.4 days), which is in agreement with the order of their reported estrogenicities. One metabolite of 4-NP(111) with less polarity than the parent compound occurred rapidly and remained stable in the soil. At the end of incubation (58 days), bound residues of 4-NP(111) amounted to 54% of the initially applied radioactivity and resided almost exclusively in the humin fraction of soil organic matter, in which chemically humin-bound residues increased over incubation. Our results indicate an increase of specific estrogenicity of the remaining 4-NPs in soil as a result of the isomer-specific degradation and therefore underline the importance of understanding the individual fate (including degradation, metabolism, and bound-residue formation) of isomers for risk assessment of 4-NPs in soil. 4-NP(1) should not be used as a representative of 4-NPs for studies on their environmental behavior.
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588 _ _ |a Dataset connected to Web of Science, Pubmed
650 _ 2 |2 MeSH
|a Carbon Isotopes
650 _ 2 |2 MeSH
|a Chemical Fractionation
650 _ 2 |2 MeSH
|a Environment
650 _ 2 |2 MeSH
|a Humic Substances: analysis
650 _ 2 |2 MeSH
|a Isomerism
650 _ 2 |2 MeSH
|a Kinetics
650 _ 2 |2 MeSH
|a Minerals: chemistry
650 _ 2 |2 MeSH
|a Oryza sativa
650 _ 2 |2 MeSH
|a Oxygen: chemistry
650 _ 2 |2 MeSH
|a Phenols: chemistry
650 _ 2 |2 MeSH
|a Radioactivity
650 _ 2 |2 MeSH
|a Soil: chemistry
650 _ 7 |0 0
|2 NLM Chemicals
|a Carbon Isotopes
650 _ 7 |0 0
|2 NLM Chemicals
|a Humic Substances
650 _ 7 |0 0
|2 NLM Chemicals
|a Minerals
650 _ 7 |0 0
|2 NLM Chemicals
|a Phenols
650 _ 7 |0 0
|2 NLM Chemicals
|a Soil
650 _ 7 |0 104-40-5
|2 NLM Chemicals
|a 4-nonylphenol
650 _ 7 |0 7782-44-7
|2 NLM Chemicals
|a Oxygen
650 _ 7 |2 WoSType
|a J
700 1 _ |0 P:(DE-HGF)0
|a Jiang, B.Q.
|b 1
700 1 _ |0 P:(DE-HGF)0
|a Yu, B.
|b 2
700 1 _ |0 P:(DE-Juel1)VDB102196
|a Li, CL.
|b 3
|u FZJ
700 1 _ |0 P:(DE-HGF)0
|a Sun, YY.
|b 4
700 1 _ |0 P:(DE-HGF)0
|a Guo, HY.
|b 5
700 1 _ |0 P:(DE-HGF)0
|a Wu, JC.
|b 6
700 1 _ |0 P:(DE-Juel1)129484
|a Klumpp, E.
|b 7
|u FZJ
700 1 _ |0 P:(DE-HGF)0
|a Schaeffer, A.
|b 8
700 1 _ |0 P:(DE-HGF)0
|a Ji, R.
|b 9
773 _ _ |0 PERI:(DE-600)1465132-4
|a 10.1021/es200224c
|g Vol. 45, p. 8283 - 8289
|p 8283 - 8289
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|t Environmental Science & Technology
|v 45
|x 0013-936X
|y 2011
856 7 _ |u http://dx.doi.org/10.1021/es200224c
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