Home > Publications database > Isomer-Specific Degradation of Branched and Linear 4-Nonylphenol Isomers in an Oxic Soil > print |
001 | 17435 | ||
005 | 20200702121610.0 | ||
024 | 7 | _ | |2 pmid |a pmid:21823570 |
024 | 7 | _ | |2 DOI |a 10.1021/es200224c |
024 | 7 | _ | |2 WOS |a WOS:000295245600047 |
024 | 7 | _ | |2 ISSN |a 0013-936X |
024 | 7 | _ | |2 ISSN |a 1520-5851 |
024 | 7 | _ | |a altmetric:379611 |2 altmetric |
037 | _ | _ | |a PreJuSER-17435 |
041 | _ | _ | |a eng |
082 | _ | _ | |a 050 |
084 | _ | _ | |2 WoS |a Engineering, Environmental |
084 | _ | _ | |2 WoS |a Environmental Sciences |
100 | 1 | _ | |0 P:(DE-HGF)0 |a Shan, J. |b 0 |
245 | _ | _ | |a Isomer-Specific Degradation of Branched and Linear 4-Nonylphenol Isomers in an Oxic Soil |
260 | _ | _ | |a Columbus, Ohio |b American Chemical Society |c 2011 |
300 | _ | _ | |a 8283 - 8289 |
336 | 7 | _ | |a Journal Article |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |
336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
336 | 7 | _ | |a ARTICLE |2 BibTeX |
336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
336 | 7 | _ | |a article |2 DRIVER |
440 | _ | 0 | |0 1865 |a Environmental Science and Technology |v 45 |x 0013-936X |y 19 |
500 | _ | _ | |3 POF3_Assignment on 2016-02-29 |
500 | _ | _ | |a This study was supported by the National Science Foundation of China (grant nos. 20777033, 20977043, and 41030746). |
520 | _ | _ | |a Using (14)C- and (13)C-ring-labeling, degradation of five p-nonylphenol (4-NP) isomers including four branched (4-NP(38), 4-NP(65), 4-NP(111), and 4-NP(112)) and one linear (4-NP(1)) isomers in a rice paddy soil was studied under oxic conditions. Degradation followed an availability-adjusted first-order kinetics with the decreasing order of half-life 4-NP(111) (10.3 days) > 4-NP(112) (8.4 days) > 4-NP(65) (5.8 days) > 4-NP(38) (2.1 days) > 4-NP(1) (1.4 days), which is in agreement with the order of their reported estrogenicities. One metabolite of 4-NP(111) with less polarity than the parent compound occurred rapidly and remained stable in the soil. At the end of incubation (58 days), bound residues of 4-NP(111) amounted to 54% of the initially applied radioactivity and resided almost exclusively in the humin fraction of soil organic matter, in which chemically humin-bound residues increased over incubation. Our results indicate an increase of specific estrogenicity of the remaining 4-NPs in soil as a result of the isomer-specific degradation and therefore underline the importance of understanding the individual fate (including degradation, metabolism, and bound-residue formation) of isomers for risk assessment of 4-NPs in soil. 4-NP(1) should not be used as a representative of 4-NPs for studies on their environmental behavior. |
536 | _ | _ | |0 G:(DE-Juel1)FUEK407 |2 G:(DE-HGF) |a Terrestrische Umwelt |c P24 |x 0 |
588 | _ | _ | |a Dataset connected to Web of Science, Pubmed |
650 | _ | 2 | |2 MeSH |a Carbon Isotopes |
650 | _ | 2 | |2 MeSH |a Chemical Fractionation |
650 | _ | 2 | |2 MeSH |a Environment |
650 | _ | 2 | |2 MeSH |a Humic Substances: analysis |
650 | _ | 2 | |2 MeSH |a Isomerism |
650 | _ | 2 | |2 MeSH |a Kinetics |
650 | _ | 2 | |2 MeSH |a Minerals: chemistry |
650 | _ | 2 | |2 MeSH |a Oryza sativa |
650 | _ | 2 | |2 MeSH |a Oxygen: chemistry |
650 | _ | 2 | |2 MeSH |a Phenols: chemistry |
650 | _ | 2 | |2 MeSH |a Radioactivity |
650 | _ | 2 | |2 MeSH |a Soil: chemistry |
650 | _ | 7 | |0 0 |2 NLM Chemicals |a Carbon Isotopes |
650 | _ | 7 | |0 0 |2 NLM Chemicals |a Humic Substances |
650 | _ | 7 | |0 0 |2 NLM Chemicals |a Minerals |
650 | _ | 7 | |0 0 |2 NLM Chemicals |a Phenols |
650 | _ | 7 | |0 0 |2 NLM Chemicals |a Soil |
650 | _ | 7 | |0 104-40-5 |2 NLM Chemicals |a 4-nonylphenol |
650 | _ | 7 | |0 7782-44-7 |2 NLM Chemicals |a Oxygen |
650 | _ | 7 | |2 WoSType |a J |
700 | 1 | _ | |0 P:(DE-HGF)0 |a Jiang, B.Q. |b 1 |
700 | 1 | _ | |0 P:(DE-HGF)0 |a Yu, B. |b 2 |
700 | 1 | _ | |0 P:(DE-Juel1)VDB102196 |a Li, CL. |b 3 |u FZJ |
700 | 1 | _ | |0 P:(DE-HGF)0 |a Sun, YY. |b 4 |
700 | 1 | _ | |0 P:(DE-HGF)0 |a Guo, HY. |b 5 |
700 | 1 | _ | |0 P:(DE-HGF)0 |a Wu, JC. |b 6 |
700 | 1 | _ | |0 P:(DE-Juel1)129484 |a Klumpp, E. |b 7 |u FZJ |
700 | 1 | _ | |0 P:(DE-HGF)0 |a Schaeffer, A. |b 8 |
700 | 1 | _ | |0 P:(DE-HGF)0 |a Ji, R. |b 9 |
773 | _ | _ | |0 PERI:(DE-600)1465132-4 |a 10.1021/es200224c |g Vol. 45, p. 8283 - 8289 |p 8283 - 8289 |q 45<8283 - 8289 |t Environmental Science & Technology |v 45 |x 0013-936X |y 2011 |
856 | 7 | _ | |u http://dx.doi.org/10.1021/es200224c |
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914 | 1 | _ | |y 2011 |
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