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@ARTICLE{Rispens:175321,
author = {Rispens, Gijsbert and Ziegler, Benedikt and Paruch,
Patrycja and Zanolli, Zeila and Íñiguez, Jorge and Ghosez,
Philippe},
title = {{P}hase diagram of
${\mathrm{{B}i{F}e{O}}}_{3}/{\mathrm{{L}a{F}e{O}}}_{3}$
superlattices studied by x-ray diffraction experiments and
first-principles calculations},
journal = {Physical review / B},
volume = {90},
number = {10},
issn = {1098-0121},
address = {College Park, Md.},
publisher = {APS},
reportid = {FZJ-2014-06839},
pages = {104106},
year = {2014},
abstract = {Combining structural and functional measurements, we have
mapped the phase diagram of BiFeO3/LaFeO3 superlattices
grown by off-axis sputtering on (110)o DyScO3 substrates.
The phase diagram displays three distinct regions as a
function of BiFeO3 fraction, with a BiFeO3-like
ferroelectric phase and a LaFeO3-like paraelectric phase at
its extremities, and a complex intermediate region, as
supported by first-principles calculations. This
intermediate region shows unusual, mixed functional
behavior, most likely due to competing phases driven by
substitution with a same-size central ion and the specific
boundary conditions imposed by the superlattice structure.
In the BiFeO3 rich superlattices, scaling of the
ferroelectric-to-paraelectric transition temperature with
the BiFeO3 thickness could provide an alternate route for
studying ferroelectric size effects in BiFeO3.},
cin = {IAS-1 / PGI-1 / JARA-FIT},
ddc = {530},
cid = {I:(DE-Juel1)IAS-1-20090406 / I:(DE-Juel1)PGI-1-20110106 /
$I:(DE-82)080009_20140620$},
pnm = {422 - Spin-based and quantum information (POF2-422)},
pid = {G:(DE-HGF)POF2-422},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000342134200004},
doi = {10.1103/PhysRevB.90.104106},
url = {https://juser.fz-juelich.de/record/175321},
}