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024 7 _ |a 10.1103/PhysRevB.90.104106
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024 7 _ |a 0163-1829
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024 7 _ |a 0556-2805
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024 7 _ |a 1095-3795
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024 7 _ |a 1098-0121
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024 7 _ |a 1550-235X
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024 7 _ |a 2128/8154
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037 _ _ |a FZJ-2014-06839
082 _ _ |a 530
100 1 _ |a Rispens, Gijsbert
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245 _ _ |a Phase diagram of ${\mathrm{BiFeO}}_{3}/{\mathrm{LaFeO}}_{3}$ superlattices studied by x-ray diffraction experiments and first-principles calculations
260 _ _ |a College Park, Md.
|c 2014
|b APS
336 7 _ |a Journal Article
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520 _ _ |a Combining structural and functional measurements, we have mapped the phase diagram of BiFeO3/LaFeO3 superlattices grown by off-axis sputtering on (110)o DyScO3 substrates. The phase diagram displays three distinct regions as a function of BiFeO3 fraction, with a BiFeO3-like ferroelectric phase and a LaFeO3-like paraelectric phase at its extremities, and a complex intermediate region, as supported by first-principles calculations. This intermediate region shows unusual, mixed functional behavior, most likely due to competing phases driven by substitution with a same-size central ion and the specific boundary conditions imposed by the superlattice structure. In the BiFeO3 rich superlattices, scaling of the ferroelectric-to-paraelectric transition temperature with the BiFeO3 thickness could provide an alternate route for studying ferroelectric size effects in BiFeO3.
536 _ _ |a 422 - Spin-based and quantum information (POF2-422)
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542 _ _ |i 2014-09-12
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700 1 _ |a Ziegler, Benedikt
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700 1 _ |a Paruch, Patrycja
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700 1 _ |a Zanolli, Zeila
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700 1 _ |a Íñiguez, Jorge
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700 1 _ |a Ghosez, Philippe
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773 1 8 |a 10.1103/physrevb.90.104106
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|t Physical Review B
|v 90
|y 2014
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773 _ _ |a 10.1103/PhysRevB.90.104106
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914 1 _ |y 2014
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Marc 21