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@ARTICLE{Malvestuto:17644,
author = {Malvestuto, M. and Carleschi, E. and Fittipaldi, R. and
Gorelov, E. and Pavarini, E. and Cuoco, M. and Maeno, Y. and
Parmigiani, F. and Vecchione, A.},
title = {{E}lectronic structure trends in the
{S}r(n+1){R}u(n){O}(3n+1) family (n=1,2,3)},
journal = {Physical review / B},
volume = {83},
number = {16},
issn = {1098-0121},
address = {College Park, Md.},
publisher = {APS},
reportid = {PreJuSER-17644},
pages = {165121},
year = {2011},
note = {E.G. and E.P. acknowledge the Julich BlueGene/P Grant No.
JIFF41, as well as financial support by the Deutsche
Forschungsgemeinschaft through the research unit FOR 1346.},
abstract = {The identification of electronic states and the analysis of
their evolution with n is key to understanding n-layered
ruthenates. To this end, we combine polarization-dependent O
1s x-ray absorption spectroscopy, high-purity Srn+1RunO3n+1
(n = 1,2,3) single crystals, and ab initio and many-body
calculations. We find that the energy splitting between the
empty x(2) - y(2) and 3z(2) - 1 state is considerably
smaller than previously suggested and that, remarkably, Sr
bands are essential to understanding the spectra. At low
energy, we identify the main difference among the materials
with a substantial rearrangement of t(2g) orbital
occupations with increasing n. This rearrangement is
controlled by the interplay of Coulomb repulsion,
dimensionality, and changes in the t(2g) crystal field.},
keywords = {J (WoSType)},
cin = {IAS-3 / PGI-2},
ddc = {530},
cid = {I:(DE-Juel1)IAS-3-20090406 / I:(DE-Juel1)PGI-2-20110106},
pnm = {Grundlagen für zukünftige Informationstechnologien},
pid = {G:(DE-Juel1)FUEK412},
shelfmark = {Physics, Condensed Matter},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000290113200003},
doi = {10.1103/PhysRevB.83.165121},
url = {https://juser.fz-juelich.de/record/17644},
}