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024 7 _ |a 10.1103/PhysRevB.83.165121
|2 DOI
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037 _ _ |a PreJuSER-17644
041 _ _ |a eng
082 _ _ |a 530
084 _ _ |2 WoS
|a Physics, Condensed Matter
100 1 _ |0 P:(DE-HGF)0
|a Malvestuto, M.
|b 0
245 _ _ |a Electronic structure trends in the Sr(n+1)Ru(n)O(3n+1) family (n=1,2,3)
260 _ _ |a College Park, Md.
|b APS
|c 2011
300 _ _ |a 165121
336 7 _ |a Journal Article
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440 _ 0 |0 4919
|a Physical Review B
|v 83
|x 1098-0121
|y 16
500 _ _ |3 POF3_Assignment on 2016-02-29
500 _ _ |a E.G. and E.P. acknowledge the Julich BlueGene/P Grant No. JIFF41, as well as financial support by the Deutsche Forschungsgemeinschaft through the research unit FOR 1346.
520 _ _ |a The identification of electronic states and the analysis of their evolution with n is key to understanding n-layered ruthenates. To this end, we combine polarization-dependent O 1s x-ray absorption spectroscopy, high-purity Srn+1RunO3n+1 (n = 1,2,3) single crystals, and ab initio and many-body calculations. We find that the energy splitting between the empty x(2) - y(2) and 3z(2) - 1 state is considerably smaller than previously suggested and that, remarkably, Sr bands are essential to understanding the spectra. At low energy, we identify the main difference among the materials with a substantial rearrangement of t(2g) orbital occupations with increasing n. This rearrangement is controlled by the interplay of Coulomb repulsion, dimensionality, and changes in the t(2g) crystal field.
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700 1 _ |0 P:(DE-HGF)0
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700 1 _ |0 P:(DE-HGF)0
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773 1 8 |a 10.1103/physrevb.83.165121
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|v 83
|y 2011
|x 1098-0121
773 _ _ |a 10.1103/PhysRevB.83.165121
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856 7 _ |u http://dx.doi.org/10.1103/PhysRevB.83.165121
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