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@ARTICLE{Lee:18271,
author = {Lee, D.-K. and Fischer, C.C. and Valov, I. and Reinacher,
J. and Stork, A. and Lerch, M. and Janek, J.},
title = {{A}n {EMF} cell with a nitrogen solid electrolyte - on the
transference of nitrogen ions in yttria-stabilized zirconia},
journal = {Physical Chemistry Chemical Physics},
volume = {13},
issn = {1463-9076},
address = {Cambridge},
publisher = {RSC Publ.},
reportid = {PreJuSER-18271},
pages = {1239 - 1242},
year = {2011},
note = {This study (DFG Ja648/ 8-3, Le781/ 10-4) was funded by the
German Science Foundation (DFG) within the priority program
1136 Substitution Effects in Ionic Solids.},
abstract = {The mobility and electrochemical activity of nitrogen
inside and/or at the surface of ionic compounds is of
fundamental, as well as of possibly practical, relevance. In
order to better understand the role of nitrogen anions in
solid electrolytes, we measured the transference number of
nitrogen in yttria-stabilized zirconia (YSZ) by a
concentration cell technique as a function of oxygen
activity at different temperatures in the range of 1023
≤T/K≤ 1123. YSZ doped with 1.9 $wt\%$ of N (YSZ:N)
turned out to have an appreciable nitrogen transference
number, which increased from 0 to 0.1 with decreasing oxygen
activity in the range of -20 < log a(O(2)) < -14. The
stability of N in YSZ:N, however, has yet to be elucidated
under oxidizing conditions.},
keywords = {J (WoSType)},
cin = {PGI-7 / JARA-FIT},
ddc = {540},
cid = {I:(DE-Juel1)PGI-7-20110106 / $I:(DE-82)080009_20140620$},
pnm = {Grundlagen für zukünftige Informationstechnologien},
pid = {G:(DE-Juel1)FUEK412},
shelfmark = {Chemistry, Physical / Physics, Atomic, Molecular $\&$
Chemical},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:21079879},
UT = {WOS:000285750100050},
doi = {10.1039/c003991h},
url = {https://juser.fz-juelich.de/record/18271},
}