001     18271
005     20180208222013.0
024 7 _ |2 pmid
|a pmid:21079879
024 7 _ |2 DOI
|a 10.1039/c003991h
024 7 _ |2 WOS
|a WOS:000285750100050
024 7 _ |2 ISSN
|a 1463-9076
024 7 _ |2 Handle
|a 2128/7363
037 _ _ |a PreJuSER-18271
041 _ _ |a eng
082 _ _ |a 540
084 _ _ |2 WoS
|a Chemistry, Physical
084 _ _ |2 WoS
|a Physics, Atomic, Molecular & Chemical
100 1 _ |0 P:(DE-HGF)0
|a Lee, D.-K.
|b 0
245 _ _ |a An EMF cell with a nitrogen solid electrolyte - on the transference of nitrogen ions in yttria-stabilized zirconia
260 _ _ |a Cambridge
|b RSC Publ.
|c 2011
300 _ _ |a 1239 - 1242
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440 _ 0 |0 4916
|a Physical Chemistry Chemical Physics
|v 13
|x 1463-9076
|y 3
500 _ _ |3 POF3_Assignment on 2016-02-29
500 _ _ |a This study (DFG Ja648/ 8-3, Le781/ 10-4) was funded by the German Science Foundation (DFG) within the priority program 1136 Substitution Effects in Ionic Solids.
520 _ _ |a The mobility and electrochemical activity of nitrogen inside and/or at the surface of ionic compounds is of fundamental, as well as of possibly practical, relevance. In order to better understand the role of nitrogen anions in solid electrolytes, we measured the transference number of nitrogen in yttria-stabilized zirconia (YSZ) by a concentration cell technique as a function of oxygen activity at different temperatures in the range of 1023 ≤T/K≤ 1123. YSZ doped with 1.9 wt% of N (YSZ:N) turned out to have an appreciable nitrogen transference number, which increased from 0 to 0.1 with decreasing oxygen activity in the range of -20 < log a(O(2)) < -14. The stability of N in YSZ:N, however, has yet to be elucidated under oxidizing conditions.
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|a Fischer, C.C.
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|a Valov, I.
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|u FZJ
700 1 _ |0 P:(DE-HGF)0
|a Reinacher, J.
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700 1 _ |0 P:(DE-HGF)0
|a Stork, A.
|b 4
700 1 _ |0 P:(DE-HGF)0
|a Lerch, M.
|b 5
700 1 _ |0 P:(DE-HGF)0
|a Janek, J.
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773 _ _ |0 PERI:(DE-600)1476244-4
|a 10.1039/c003991h
|g Vol. 13, p. 1239 - 1242
|p 1239 - 1242
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|t Physical Chemistry Chemical Physics
|v 13
|x 1463-9076
|y 2011
856 7 _ |u http://dx.doi.org/10.1039/c003991h
856 4 _ |u https://juser.fz-juelich.de/record/18271/files/FZJ-18271.pdf
|y Published under German "Allianz" Licensing conditions on 2010-11-16. Available in OpenAccess from 2011-11-16
|z Published final document.
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914 1 _ |y 2011
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