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@ARTICLE{Lon:18310,
      author       = {Léon, A. and Wuttke, J.},
      title        = {{H}ydrogen {R}elease from {S}odium {A}lanate {O}bserved by
                      {T}ime-resolved {N}eutron {B}ackscattering},
      journal      = {Journal of physics / Condensed matter},
      volume       = {23},
      issn         = {0953-8984},
      address      = {Bristol},
      publisher    = {IOP Publ.},
      reportid     = {PreJuSER-18310},
      pages        = {254214},
      year         = {2011},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {Innermolecular motion in Na(3)AlH(6) gives rise to a
                      Lorentzian spectrum with a wavenumber-independent width of
                      about 1  µeV at 180 °C, which is probably due to the
                      rotation of AlH(6) tetrahedra. There is no such quasielastic
                      line in NaAlH(4) or NaH. Based on this finding,
                      time-resolved measurements on the neutron backscattering
                      spectrometer SPHERES were used to monitor the decomposition
                      kinetics of sodium alanate, [Formula: see text] NaH. Both
                      reaction steps were found to be accelerated by
                      autocatalysis, most likely at the surfaces of Na(3)AlH(6)
                      and NaH crystallites.},
      keywords     = {J (WoSType)},
      cin          = {ICS-1 / JCNS (München) ; Jülich Centre for Neutron
                      Science JCNS (München) ; JCNS-FRM-II / JCNS-1 / JCNS-2},
      ddc          = {530},
      cid          = {I:(DE-Juel1)ICS-1-20110106 /
                      I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-1-20110106 / I:(DE-Juel1)JCNS-2-20110106},
      pnm          = {BioSoft: Makromolekulare Systeme und biologische
                      Informationsverarbeitung / Großgeräte für die Forschung
                      mit Photonen, Neutronen und Ionen (PNI)},
      pid          = {G:(DE-Juel1)FUEK505 / G:(DE-Juel1)FUEK415},
      experiment   = {EXP:(DE-MLZ)SPHERES-20140101},
      shelfmark    = {Physics, Condensed Matter},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:21654051},
      UT           = {WOS:000291433000017},
      doi          = {10.1088/0953-8984/23/25/254214},
      url          = {https://juser.fz-juelich.de/record/18310},
}