001     18310
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024 7 _ |2 pmid
|a pmid:21654051
024 7 _ |2 DOI
|a 10.1088/0953-8984/23/25/254214
024 7 _ |2 WOS
|a WOS:000291433000017
024 7 _ |2 MLZ
|a LeonW2011
037 _ _ |a PreJuSER-18310
041 _ _ |a eng
082 _ _ |a 530
084 _ _ |2 WoS
|a Physics, Condensed Matter
100 1 _ |0 P:(DE-HGF)0
|a Léon, A.
|b 0
245 _ _ |a Hydrogen Release from Sodium Alanate Observed by Time-resolved Neutron Backscattering
260 _ _ |a Bristol
|b IOP Publ.
|c 2011
300 _ _ |a 254214
336 7 _ |a Journal Article
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336 7 _ |a ARTICLE
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336 7 _ |a article
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440 _ 0 |0 3703
|a Journal of Physics: Condensed Matter
|v 23
|x 0953-8984
|y 25
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a Innermolecular motion in Na(3)AlH(6) gives rise to a Lorentzian spectrum with a wavenumber-independent width of about 1  µeV at 180 °C, which is probably due to the rotation of AlH(6) tetrahedra. There is no such quasielastic line in NaAlH(4) or NaH. Based on this finding, time-resolved measurements on the neutron backscattering spectrometer SPHERES were used to monitor the decomposition kinetics of sodium alanate, [Formula: see text] NaH. Both reaction steps were found to be accelerated by autocatalysis, most likely at the surfaces of Na(3)AlH(6) and NaH crystallites.
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|a Großgeräte für die Forschung mit Photonen, Neutronen und Ionen (PNI)
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650 2 7 |a Materials Science
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650 1 7 |a Energy
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693 _ _ |0 EXP:(DE-MLZ)SPHERES-20140101
|1 EXP:(DE-MLZ)FRMII-20140101
|5 EXP:(DE-MLZ)SPHERES-20140101
|6 EXP:(DE-MLZ)NL6S-20140101
|a Forschungs-Neutronenquelle Heinz Maier-Leibnitz
|e SPHERES: Backscattering spectrometer
|f NL6S
|x 0
700 1 _ |0 P:(DE-Juel1)131044
|a Wuttke, J.
|b 1
|u FZJ
773 _ _ |0 PERI:(DE-600)1472968-4
|a 10.1088/0953-8984/23/25/254214
|g Vol. 23, p. 254214
|p 254214
|q 23<254214
|t Journal of physics / Condensed matter
|v 23
|x 0953-8984
|y 2011
856 7 _ |u http://dx.doi.org/10.1088/0953-8984/23/25/254214
909 C O |o oai:juser.fz-juelich.de:18310
|p VDB:MLZ
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|l Biologische Informationsverarbeitung
|v BioSoft: Makromolekulare Systeme und biologische Informationsverarbeitung
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913 1 _ |0 G:(DE-Juel1)FUEK415
|b Struktur der Materie
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913 2 _ |0 G:(DE-HGF)POF3-623
|1 G:(DE-HGF)POF3-620
|2 G:(DE-HGF)POF3-600
|a DE-HGF
|b Forschungsbereich Materie
|l In-house research on the structure, dynamics and function of matter
|v Neutrons for Research on Condensed Matter
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914 1 _ |y 2011
915 _ _ |0 StatID:(DE-HGF)0010
|a JCR/ISI refereed
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