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@ARTICLE{Papagiannopoulos:185715,
author = {Papagiannopoulos, Aristeidis and Zhao, Junpeng and Zhang,
Guangzhao and Pispas, Stergios and Radulescu, Aurel},
title = {{T}hermoresponsive aggregation of {PS}-{PNIPAM}-{PS}
triblock copolymer: {A} combined study of light scattering
and small angle neutron scattering},
journal = {European polymer journal},
volume = {56},
issn = {0014-3057},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2014-07140},
pages = {59 - 68},
year = {2014},
abstract = {The aggregate structure of a thermoresponsive
polystyrene–b-poly(N-isopropylacrylamide)–b-polystyrene
(PS–PNIPAM–PS) triblock copolymer was investigated as a
function of temperature in aqueous solutions by the
combination of small angle neutron scattering (SANS) and
dynamic/static light scattering (LS). SANS shows that the
system consists of spherical intermicellar aggregates which
self-assemble into larger clusters either at temperatures
below or above the lower critical solution temperature
(LCST). Upon the solubility transition of PNIPAM the mass of
the clusters increases significantly, whereas their size
remains constant and the size of the intermicellar
aggregates decreases. This picture is consistent with the LS
data where the signature of the two entities in solution is
observed. The combination of LS and SANS studies has
presented a clearer scenario on the thermoresponsive
aggregation behavior of the investigated PS–PNIPAM–PS
triblock copolymer.},
cin = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
(München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1 /
ICS-1},
ddc = {670},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-1-20110106 / I:(DE-Juel1)ICS-1-20110106},
pnm = {451 - Soft Matter Composites (POF2-451) / 54G - JCNS
(POF2-54G24)},
pid = {G:(DE-HGF)POF2-451 / G:(DE-HGF)POF2-54G24},
experiment = {EXP:(DE-MLZ)KWS1-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000338392000007},
doi = {10.1016/j.eurpolymj.2014.04.013},
url = {https://juser.fz-juelich.de/record/185715},
}