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000185828 0247_ $$2doi$$a10.1021/la404918b
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000185828 1001_ $$0P:(DE-HGF)0$$aWang, Jingbo$$b0$$eCorresponding Author
000185828 245__ $$aMonolayer Properties of Asymmetrically Substituted Sexithiophene
000185828 260__ $$aWashington, DC$$bACS Publ.$$c2014
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000185828 520__ $$aWe present a structural comparison of monolayers on a SiO2 substrate of two asymmetrically substituted sexithiophenes (6T). Molecule 1 consists of 6T with a branched alkyl chain at one end only and shows a crystalline structure. In molecule 2, the bifunctional 6T has in addition at the other end a linear alkyl chain. It displays thermotropic liquid crystalline (LC) behavior. Both compounds form readily single molecular layers from solution. Remarkably, full monolayer coverage can be achieved before multilayer growth starts. LC properties promote preordering near the interface as well as exchange of molecules between the growing domains, thus regulating the domain sizes. As a result, the LC compound 2 forms single-molecule islands with larger domain sizes compared to compound 1. Surface X-ray investigations indicate that the 6T cores are tilted relative to the layer normal. The tilt angle is as large as 54° for compound 2 compared to 28° for compound 1. For molecule 2, interfacial constraints and packing requirements because of the asymmetric substitution cause a rather loosely organized core structure.
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000185828 7001_ $$0P:(DE-HGF)0$$aZiener, Ulrich$$b2
000185828 7001_ $$0P:(DE-HGF)0$$aPolinskaya, Marina S.$$b3
000185828 7001_ $$0P:(DE-HGF)0$$aPonomarenko, Sergei A.$$b4
000185828 7001_ $$0P:(DE-HGF)0$$aRuderer, Matthias A.$$b5
000185828 7001_ $$0P:(DE-HGF)0$$aHerzig, Eva M.$$b6
000185828 7001_ $$0P:(DE-HGF)0$$aMüller-Buschbaum, Peter$$b7
000185828 7001_ $$0P:(DE-HGF)0$$aMoeller, Martin$$b8
000185828 7001_ $$0P:(DE-HGF)0$$aMourran, Ahmed$$b9
000185828 7001_ $$0P:(DE-Juel1)130928$$aRücker, Ulrich$$b10
000185828 773__ $$0PERI:(DE-600)2005937-1$$a10.1021/la404918b$$gVol. 30, no. 10, p. 2752 - 2760$$n10$$p2752 - 2760$$tLangmuir$$v30$$x1520-5827$$y2014
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