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@ARTICLE{Brodeck:186176,
author = {Brodeck, Martin and Maccarrone, Simona and Saha, Debasish
and Willner, Lutz and Allgaier, J. and Mangiapia, Gaetano
and Frielinghaus, Henrich and Holderer, Olaf and Faraone,
Antonio and Richter, Dieter},
title = {{A}symmetric polymers in bicontinuous microemulsions and
their accretion to the bending of the membrane},
journal = {Colloid $\&$ polymer science},
volume = {293},
number = {4},
issn = {1435-1536},
address = {Berlin},
publisher = {Springer},
reportid = {FZJ-2015-00264},
pages = {1253-1265},
year = {2015},
abstract = {After linear hydrophilic polymers with a short hydrophobic
sticker have been proven to be highly suitable as efficiency
boosters in microemulsions, a whole set of asymmetric
polymers was studied in more detail. Sticker polymers with
two hydrophilic polymeric arms, hydrophobic polymers with
ionic stickers, and a Y-shaped tri-arm-polymer were studied
for their high surface activity. While low asymmetry of the
Y-shaped polymer resulted in very similar dependence as a
diblock copolymer, the highly asymmetric polymers showed a
renormalized behavior of the bending rigidity coming from
preferential accretion of the polymer at the membrane. The
experimental evidence for the accretion of the polymer
according to the preferential membrane bending is reported
here for the first time. Furthermore, the isolated, diffuse
counter ion clouds of the ionic sticker polymers act in a
way similar to that of a polymer anchored at the membrane.
All asymmetric polymers are highly suitable as efficiency
boosters in microemulsions.},
cin = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
(München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1},
ddc = {540},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-1-20110106},
pnm = {6G15 - FRM II / MLZ (POF3-6G15) / 6G4 - Jülich Centre for
Neutron Research (JCNS) (POF3-623)},
pid = {G:(DE-HGF)POF3-6G15 / G:(DE-HGF)POF3-6G4},
experiment = {EXP:(DE-MLZ)KWS2-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000352074200026},
doi = {10.1007/s00396-014-3449-8},
url = {https://juser.fz-juelich.de/record/186176},
}