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@ARTICLE{Breinlich:186405,
      author       = {Breinlich, Christian and Buchholz, Maria and Moors, Marco
                      and Le Moal, Séverine and Becker, Conrad and Wandelt,
                      Klaus},
      title        = {{S}canning {T}unneling {M}icroscopy {I}nvestigation of
                      {U}ltrathin {T}itanium {O}xide {F}ilms {G}rown on {P}t 3
                      {T}i(111)},
      journal      = {The journal of physical chemistry / C},
      volume       = {118},
      number       = {12},
      issn         = {1932-7455},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2015-00481},
      pages        = {6186 - 6192},
      year         = {2014},
      abstract     = {Ordered ultrathin titanium oxide films have been produced
                      under ultrahigh vacuum (UHV) conditions by oxidation of a
                      Pt3Ti(111) single crystal at elevated temperatures.
                      Depending on substrate temperature, oxygen dosage, and
                      partial pressure, four different titania phases have been
                      observed. All phases have been investigated by low-energy
                      electron diffraction (LEED) and scanning tunneling
                      microscopy (STM). Two commensurate phases with a rect-(6 ×
                      3√3) and a hex-(7 × 7)R21.8° superstructure,
                      respectively, are obtained at low oxygen pressures. Both
                      structures form homogeneous films, which wet the complete
                      surface and are stable against further annealing. At high
                      oxygen partial pressures two incommensurate structures can
                      be prepared. The first one contains several holes to release
                      stress arising from the lattice mismatch between the oxide
                      film and substrate. The second one shows a very rough
                      surface morphology and is, like the other incommensurate
                      phase, unstable against thermal treatment. The structures of
                      the different phases are very similar to the structures
                      found for the systems TiOx/Pt(111), VOx/Rh(111), and
                      VOx/Pd(111), which have been described extensively in the
                      literature.},
      cin          = {PGI-7},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-7-20110106},
      pnm          = {421 - Frontiers of charge based Electronics (POF2-421)},
      pid          = {G:(DE-HGF)POF2-421},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000333578300022},
      doi          = {10.1021/jp4105213},
      url          = {https://juser.fz-juelich.de/record/186405},
}