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@ARTICLE{Mazurowski:186449,
author = {Mazurowski, Markus and Sondergeld, Katrin and Elbert,
Johannes and Kim, Chang Jong and Li, Junyu and Frielinghaus,
Henrich and Gallei, Markus and Stühn, Bernd and Rehahn,
Matthias},
title = {{P}olystyrene {B}rushes on {F}ully {D}euterated {O}rganic
{N}anoparticles by {S}urface-{I}nitiated
{N}itroxide-{M}ediated {R}adical {P}olymerization},
journal = {Macromolecular chemistry and physics},
volume = {214},
number = {10},
issn = {1022-1352},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2015-00523},
pages = {1094 - 1106},
year = {2013},
abstract = {The synthesis of polystyrene (PS) brushes on fully
deuterated PS nanoparticles by surface-initiated
nitroxide-mediated radical polymerization (SI-NMRP) is
reported. Due to the high demand of deuterated monomers, an
efficient deuteration procedure of suitable and readily
available precursors is developed. SI-NMRP of styrene is
improved regarding reaction control, grafting density, and
conversion. Insights into the scaling behavior and
conformational features of surface-attached PS chains on
deuterated particles are investigated by using dynamic light
scattering measurements, proving that polymer brushes are
formed. The particles with surface-attached initiator are
shown to be uniform spherical core-shell particles by
small-angle neutron scattering measurements.},
cin = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
(München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1 /
ICS-1},
ddc = {540},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-1-20110106 / I:(DE-Juel1)ICS-1-20110106},
pnm = {451 - Soft Matter Composites (POF2-451) / 54G - JCNS
(POF2-54G24)},
pid = {G:(DE-HGF)POF2-451 / G:(DE-HGF)POF2-54G24},
experiment = {EXP:(DE-MLZ)KWS1-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000319020600004},
doi = {10.1002/macp.201200733},
url = {https://juser.fz-juelich.de/record/186449},
}