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@ARTICLE{Huck:187298,
author = {Huck, C. and Poghossian, Arshak and Bäcker, M. and
Chaudhuri, S. and Zander, W. and Schubert, J. and Begoyan,
V. K. and Buniatyan, V. V. and Wagner, P. and Schöning, M.
J.},
title = {{C}apacitively coupled electrolyte-conductivity sensor
based on high-k material of barium strontium titanate},
journal = {Sensors and actuators / B},
volume = {198},
issn = {0925-4005},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2015-00970},
pages = {102 - 109},
year = {2014},
abstract = {A miniaturized capacitively coupled contactless
conductivity detection (C4D) sensor based on high-k
perovskite oxide of barium strontium titanate (BST) has been
implemented for the first time. The BST films (∼120 nm
thick) of Ba0.25Sr0.75TiO3 composition were prepared on a
p-Si-SiO2-Pt structure by pulsed laser deposition technique
using BST targets fabricated by the self-propagating
high-temperature synthesis method. The Pt electrodes were
buried into the SiO2 layer to obtain a planar structure. For
comparison, contact-mode electrolyte-conductivity (EC)
sensors without the protective BST layer were also
fabricated. To study the influence of the protective BST
layer, both sensors were characterized in electrolyte
solutions with various conductivities using two- and
four-electrode operation modes. The impedance spectra were
recorded in a frequency range from 1 Hz to 1 MHz. An
equivalent circuit of the C4D sensor is discussed as
well.Both, the EC and C4D sensor, demonstrate nearly
identical sensor characteristics. The obtained results
clearly show the benefits of the use of the BST-based C4D
sensor in a four-electrode configuration for contactless
conductivity measurements. A linear dependence between the
measured conductance and the electrolyte conductivity is
obtained in a wide range of electrolyte conductivity from
0.3 mS/cm to 50 mS/cm. Moreover, typical problems associated
with contact-mode EC detection such as the effect of
possible redox processes, contamination and fouling of
electrodes during continuous measurements can be minimized,
thus, enhancing the life-time of conductivity sensors
considerably.},
cin = {PGI-8 / JARA-FIT / PGI-9},
ddc = {530},
cid = {I:(DE-Juel1)PGI-8-20110106 / $I:(DE-82)080009_20140620$ /
I:(DE-Juel1)PGI-9-20110106},
pnm = {423 - Sensorics and bioinspired systems (POF2-423)},
pid = {G:(DE-HGF)POF2-423},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000335580100016},
doi = {10.1016/j.snb.2014.02.103},
url = {https://juser.fz-juelich.de/record/187298},
}