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@ARTICLE{MalodeMolina:187506,
      author       = {Malo de Molina, Paula and Appavou, Marie-Sousai and
                      Gradzielski, Michael},
      title        = {{O}il-in-water microemulsion droplets of {TDMAO}/decane
                      interconnected by the telechelic {C}18-{EO}150-{C}18:
                      clustering and network formation},
      journal      = {Soft matter},
      volume       = {10},
      number       = {28},
      issn         = {1744-6848},
      address      = {London},
      publisher    = {Royal Soc. of Chemistry},
      reportid     = {FZJ-2015-01135},
      pages        = {5072-5084},
      year         = {2014},
      abstract     = {The effect of a doubly hydrophobically end-capped water
                      soluble polymer (C18-PEO150-C18) on the properties of an
                      oil-in-water (O/W) droplet microemulsion (R [similar] 2.85
                      nm) has been studied as a function of the amount of added
                      telechelic polymer. Macroscopically one observes a
                      substantial increase of viscosity once a concentration of
                      [similar]5 hydrophobic stickers per droplet is surpassed and
                      effective cross-linking of the droplets takes place. SANS
                      measurements show that the size of the individual droplets
                      is not affected by the polymer addition but it induces
                      attractive interactions at low concentration and repulsive
                      ones at high polymer content. Measurements of the diffusion
                      coefficient by DLS and FCS show increasing sizes at low
                      polymer addition that can be attributed to the formation of
                      clusters of microemulsion droplets interconnected by the
                      polymer. At higher polymer content the network formation
                      leads to an additional slow relaxation mode in DLS that can
                      be related to the rheological behaviour, while the
                      self-diffusion observed in FCS attains a lower plateau
                      value, i.e., the microemulsion droplets remain effectively
                      fixed within the network. The combination of SANS, DLS, and
                      FCS allows us to derive a self-consistent picture of the
                      evolution of structure and dynamics of the mixed system
                      microemulsion/telechelic polymer as a function of the
                      polymer content, which is not only relevant for controlling
                      the macroscopic rheological properties but also with respect
                      to the internal dynamics as it is, for instance, relevant
                      for the release and transport of active agents.},
      cin          = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
                      (München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1 /
                      ICS-1},
      ddc          = {530},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-1-20110106 / I:(DE-Juel1)ICS-1-20110106},
      pnm          = {54G - JCNS (POF2-54G24)},
      pid          = {G:(DE-HGF)POF2-54G24},
      experiment   = {EXP:(DE-MLZ)KWS1-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000338644400006},
      pubmed       = {pmid:24901947},
      doi          = {10.1039/c4sm00501e},
      url          = {https://juser.fz-juelich.de/record/187506},
}