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000187531 1001_ $$0P:(DE-HGF)0$$aOhrt, C.$$b0
000187531 245__ $$aInterphases in Polymer Solid-Contacts and Nanocomposites Probed by Positron Annihilation Lifetime Spectroscopy
000187531 260__ $$aLondon [u.a.] Taylor & Francis$$bTaylor & Francis$$c2014
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000187531 520__ $$aAt polymer-solid contacts with thermoplastic polymers, the chain characteristics can deviate from the bulk on a length-scale of several nanometer in the so-called interphase. Such an interphase depends on the interaction between respective macromolecule and substrate, and affects the free volume in the polymer. Here, we review our experiments on the characterization of the free volume by positron lifetime spectroscopy at planar and curved interfaces. For Teflon AF on silicon, we identify a layer of increased density, corresponding to an interphase width of some 10 nm. PEP based nanocomposites with functionalized silica show no interphase, whereas for functionalized POSS an interphase is detected.
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000187531 65017 $$0V:(DE-MLZ)GC-1603-2016$$2V:(DE-HGF)$$aChemical Reactions and Advanced Materials$$x1
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000187531 693__ $$0EXP:(DE-MLZ)NEPOMUC-20140101$$1EXP:(DE-MLZ)FRMII-20140101$$5EXP:(DE-MLZ)NEPOMUC-20140101$$6EXP:(DE-MLZ)SR11-20140101$$aForschungs-Neutronenquelle Heinz Maier-Leibnitz $$eNEPOMUC: Neutron induced positron source munich$$fSR11$$x0
000187531 7001_ $$0P:(DE-HGF)0$$aKoschine, T.$$b1
000187531 7001_ $$0P:(DE-HGF)0$$aHarms, S.$$b2
000187531 7001_ $$0P:(DE-HGF)0$$aFaupel, F.$$b3
000187531 7001_ $$0P:(DE-HGF)0$$aRätzke, K.$$b4$$eCollaboration Author
000187531 7001_ $$0P:(DE-HGF)0$$aEgger, W.$$b5
000187531 7001_ $$0P:(DE-HGF)0$$aRavelli, L.$$b6
000187531 7001_ $$0P:(DE-Juel1)131036$$aWillner, L.$$b7
000187531 7001_ $$0P:(DE-Juel1)130949$$aSchneider, G. J.$$b8$$eCorresponding Author
000187531 773__ $$0PERI:(DE-600)2178402-4$$a10.1080/1539445X.2014.957835$$gVol. 12, no. sup1, p. S135 - S141$$nSupplement 1$$pS135 - S141$$tSoft materials$$v12$$x1539-4468$$y2014
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