000187533 001__ 187533
000187533 005__ 20240619091750.0
000187533 0247_ $$2doi$$a10.1103/PhysRevLett.113.238305
000187533 0247_ $$2ISSN$$a0031-9007
000187533 0247_ $$2ISSN$$a1079-7114
000187533 0247_ $$2Handle$$a2128/8338
000187533 0247_ $$2WOS$$aWOS:000346836400010
000187533 037__ $$aFZJ-2015-01162
000187533 082__ $$a550
000187533 1001_ $$0P:(DE-Juel1)141611$$aZinn, Thomas$$b0$$eCorresponding Author
000187533 245__ $$aNanoscopic Confinement through Self-Assembly: Crystallization within Micellar Cores Exhibits Simple Gibbs-Thomson Behavior
000187533 260__ $$aCollege Park, Md.$$bAPS$$c2014
000187533 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1422618790_14513
000187533 3367_ $$2DataCite$$aOutput Types/Journal article
000187533 3367_ $$00$$2EndNote$$aJournal Article
000187533 3367_ $$2BibTeX$$aARTICLE
000187533 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000187533 3367_ $$2DRIVER$$aarticle
000187533 520__ $$aIt is well known that liquids confined to small nanoscopic pores and droplets exhibit thermal behavior very different from bulk samples. Less is known about liquids spontaneously confined through self-assembly into micellar structures. Here we demonstrate, using a very well-defined n-alkyl-poly(ethylene oxide) polymer system with a tunable structure, that n-alkane(s) forming 2–3 nm small micellar cores are affected considerably by confinement in the form of melting point depressions. Moreover, comparing the reduction in melting points, ΔTm, determined through volumetric and calorimetric methods with the micellar core radius, Rc, obtained from small-angle x-ray scattering, we find excellent agreement with the well-known Gibbs-Thomson equation, ΔTm∼R−1c. This demonstrates that the reduced size, i.e., the Laplace pressure, is the dominant parameter governing the melting point depression in micellar systems.
000187533 536__ $$0G:(DE-HGF)POF2-451$$a451 - Soft Matter Composites (POF2-451)$$cPOF2-451$$fPOF II$$x0
000187533 536__ $$0G:(DE-HGF)POF2-54G24$$a54G - JCNS (POF2-54G24)$$cPOF2-54G24$$fPOF II$$x1
000187533 588__ $$aDataset connected to CrossRef, juser.fz-juelich.de
000187533 7001_ $$0P:(DE-Juel1)131036$$aWillner, Lutz$$b1$$ufzj
000187533 7001_ $$0P:(DE-HGF)0$$aLund, Reidar$$b2
000187533 773__ $$0PERI:(DE-600)1472655-5$$a10.1103/PhysRevLett.113.238305$$gVol. 113, no. 23, p. 238305$$n23$$p238305$$tPhysical review letters$$v113$$x1079-7114$$y2014
000187533 8564_ $$uhttps://juser.fz-juelich.de/record/187533/files/FZJ-2015-01162.pdf$$yOpenAccess
000187533 8564_ $$uhttps://juser.fz-juelich.de/record/187533/files/FZJ-2015-01162.jpg?subformat=icon-144$$xicon-144$$yOpenAccess
000187533 8564_ $$uhttps://juser.fz-juelich.de/record/187533/files/FZJ-2015-01162.jpg?subformat=icon-180$$xicon-180$$yOpenAccess
000187533 8564_ $$uhttps://juser.fz-juelich.de/record/187533/files/FZJ-2015-01162.jpg?subformat=icon-640$$xicon-640$$yOpenAccess
000187533 909CO $$ooai:juser.fz-juelich.de:187533$$pdnbdelivery$$pVDB$$pdriver$$popen_access$$popenaire
000187533 915__ $$0LIC:(DE-HGF)APS-112012$$2HGFVOC$$aAmerican Physical Society Transfer of Copyright Agreement
000187533 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR
000187533 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000187533 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000187533 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000187533 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000187533 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000187533 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000187533 915__ $$0StatID:(DE-HGF)0310$$2StatID$$aDBCoverage$$bNCBI Molecular Biology Database
000187533 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz
000187533 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000187533 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences
000187533 915__ $$0StatID:(DE-HGF)9905$$2StatID$$aIF >= 5
000187533 9141_ $$y2014
000187533 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)131036$$aForschungszentrum Jülich GmbH$$b1$$kFZJ
000187533 9132_ $$0G:(DE-HGF)POF3-551$$1G:(DE-HGF)POF3-550$$2G:(DE-HGF)POF3-500$$aDE-HGF$$bKey Technologies$$lBioSoft – Fundamentals for future Technologies in the fields of Soft Matter and Life Sciences$$vFunctional Macromolecules and Complexes$$x0
000187533 9132_ $$0G:(DE-HGF)POF3-623$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$9G:(DE-HGF)POF3-6G4$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vFacility topic: Neutrons for Research on Condensed Matter$$x1
000187533 9132_ $$0G:(DE-HGF)POF3-621$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$9G:(DE-HGF)POF3-6215$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vIn-house research on the structure, dynamics and function of matter$$x2
000187533 9131_ $$0G:(DE-HGF)POF2-451$$1G:(DE-HGF)POF2-450$$2G:(DE-HGF)POF2-400$$3G:(DE-HGF)POF2$$4G:(DE-HGF)POF$$aDE-HGF$$bSchlüsseltechnologien$$lBioSoft$$vSoft Matter Composites$$x0
000187533 9131_ $$0G:(DE-HGF)POF2-54G24$$1G:(DE-HGF)POF2-540$$2G:(DE-HGF)POF2-500$$3G:(DE-HGF)POF2$$4G:(DE-HGF)POF$$aDE-HGF$$bStruktur der Materie$$lForschung mit Photonen, Neutronen, Ionen$$vJCNS$$x1
000187533 9201_ $$0I:(DE-Juel1)ICS-1-20110106$$kICS-1$$lNeutronenstreuung$$x0
000187533 9201_ $$0I:(DE-Juel1)JCNS-1-20110106$$kNeutronenstreuung ; JCNS-1$$lNeutronenstreuung$$x1
000187533 9801_ $$aFullTexts
000187533 980__ $$ajournal
000187533 980__ $$aVDB
000187533 980__ $$aUNRESTRICTED
000187533 980__ $$aFullTexts
000187533 980__ $$aI:(DE-Juel1)ICS-1-20110106
000187533 980__ $$aI:(DE-Juel1)JCNS-1-20110106
000187533 981__ $$aI:(DE-Juel1)IBI-8-20200312
000187533 981__ $$aI:(DE-Juel1)JCNS-1-20110106
000187533 981__ $$aI:(DE-Juel1)JCNS-1-20110106