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@ARTICLE{Zinn:187533,
      author       = {Zinn, Thomas and Willner, Lutz and Lund, Reidar},
      title        = {{N}anoscopic {C}onfinement through {S}elf-{A}ssembly:
                      {C}rystallization within {M}icellar {C}ores {E}xhibits
                      {S}imple {G}ibbs-{T}homson {B}ehavior},
      journal      = {Physical review letters},
      volume       = {113},
      number       = {23},
      issn         = {1079-7114},
      address      = {College Park, Md.},
      publisher    = {APS},
      reportid     = {FZJ-2015-01162},
      pages        = {238305},
      year         = {2014},
      abstract     = {It is well known that liquids confined to small nanoscopic
                      pores and droplets exhibit thermal behavior very different
                      from bulk samples. Less is known about liquids spontaneously
                      confined through self-assembly into micellar structures.
                      Here we demonstrate, using a very well-defined
                      n-alkyl-poly(ethylene oxide) polymer system with a tunable
                      structure, that n-alkane(s) forming 2–3 nm small micellar
                      cores are affected considerably by confinement in the form
                      of melting point depressions. Moreover, comparing the
                      reduction in melting points, ΔTm, determined through
                      volumetric and calorimetric methods with the micellar core
                      radius, Rc, obtained from small-angle x-ray scattering, we
                      find excellent agreement with the well-known Gibbs-Thomson
                      equation, ΔTm∼R−1c. This demonstrates that the reduced
                      size, i.e., the Laplace pressure, is the dominant parameter
                      governing the melting point depression in micellar systems.},
      cin          = {ICS-1 / Neutronenstreuung ; JCNS-1},
      ddc          = {550},
      cid          = {I:(DE-Juel1)ICS-1-20110106 / I:(DE-Juel1)JCNS-1-20110106},
      pnm          = {451 - Soft Matter Composites (POF2-451) / 54G - JCNS
                      (POF2-54G24)},
      pid          = {G:(DE-HGF)POF2-451 / G:(DE-HGF)POF2-54G24},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000346836400010},
      doi          = {10.1103/PhysRevLett.113.238305},
      url          = {https://juser.fz-juelich.de/record/187533},
}