% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Kyriakos:187538,
      author       = {Kyriakos, Konstantinos and Aravopoulou, Dionysia and
                      Augsbach, Lukas and Sapper, Josef and Ottinger, Sarah and
                      Psylla, Christina and Aghebat Rafat, Ali and
                      Benitez-Montoya, Carlos Adrian and Miasnikova, Anna and Di,
                      Zhenyu and Laschewsky, André and Müller-Buschbaum, Peter
                      and Kyritsis, Apostolos and Papadakis, Christine M.},
      title        = {{N}ovel thermoresponsive block copolymers having different
                      architectures—structural, rheological, thermal, and
                      dielectric investigations},
      journal      = {Colloid $\&$ polymer science},
      volume       = {292},
      number       = {8},
      issn         = {1435-1536},
      address      = {Berlin},
      publisher    = {Springer},
      reportid     = {FZJ-2015-01167},
      pages        = {1757 - 1774},
      year         = {2014},
      abstract     = {Thermoresponsive block copolymers comprising long,
                      hydrophilic, nonionic poly(methoxy diethylene glycol
                      acrylate) (PMDEGA) blocks and short hydrophobic polystyrene
                      (PS) blocks are investigated in aqueous solution. Various
                      architectures, namely diblock, triblock, and starblock
                      copolymers are studied as well as a PMDEGA homopolymer as
                      reference, over a wide concentration range. For specific
                      characterization methods, polymers were labeled, either by
                      partial deuteration (for neutron scattering studies) or by
                      fluorophores. Using fluorescence correlation spectroscopy,
                      critical micellization concentrations are identified and the
                      hydrodynamic radii of the micelles, r h mic , are
                      determined. Using dynamic light scattering, the behavior of
                      r h mic in dependence on temperature and the cloud points
                      are measured. Small-angle neutron scattering enabled the
                      detailed structural investigation of the micelles and their
                      aggregates below and above the cloud point. Viscosity
                      measurements are carried out to determine the activation
                      energies in dependence on the molecular architecture.
                      Differential scanning calorimetry at high polymer
                      concentration reveals the glass transition of the polymers,
                      the fraction of uncrystallized water and effects of the
                      phase transition at the cloud point. Dielectric relaxation
                      spectroscopy shows that the polarization changes reversibly
                      at the cloud point, which reflects the formation of large
                      aggregates upon heating through the cloud point and their
                      redissolution upon cooling.},
      cin          = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
                      (München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1 /
                      ICS-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-1-20110106 / I:(DE-Juel1)ICS-1-20110106},
      pnm          = {54G - JCNS (POF2-54G24)},
      pid          = {G:(DE-HGF)POF2-54G24},
      experiment   = {EXP:(DE-MLZ)KWS2-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000339888900004},
      doi          = {10.1007/s00396-014-3282-0},
      url          = {https://juser.fz-juelich.de/record/187538},
}