001 | 187549 | ||
005 | 20240619092103.0 | ||
024 | 7 | _ | |2 doi |a 10.1021/ma402439v |
024 | 7 | _ | |2 ISSN |a 0024-9297 |
024 | 7 | _ | |2 ISSN |a 1520-5835 |
024 | 7 | _ | |2 WOS |a WOS:000330543500034 |
037 | _ | _ | |a FZJ-2015-01178 |
082 | _ | _ | |a 540 |
100 | 1 | _ | |0 P:(DE-HGF)0 |a Hiroi, Takashi |b 0 |e Corresponding Author |
245 | _ | _ | |a Multiscale Dynamics of Inhomogeneity-Free Polymer Gels |
260 | _ | _ | |a Washington, DC |b Soc. |c 2014 |
336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1422619824_18652 |2 PUB:(DE-HGF) |
336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
336 | 7 | _ | |a ARTICLE |2 BibTeX |
336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
336 | 7 | _ | |a article |2 DRIVER |
520 | _ | _ | |a For precise understanding of the dynamics of gels, it is necessary to distinguish the effect of inherent cross-linking from accompanying inhomogeneity. This separation is realized by the use of inhomogeneity-free gel such as Tetra-PEG gel. We investigated the dynamics of Tetra-PEG gel by quasi-elastic scattering. Mesoscopic (length scale: ∼100 nm) motion was measured by dynamic light scattering (DLS). In addition to this scale, we used neutron spin echo (NSE) to measure microscopic (length scale: ∼1 nm) motion. From these measurements, it is revealed that the gels with no connectivity/topological inhomogeneities show the transition from Zimm mode to collective diffusion mode in larger length scale, even beyond the q-range of NSE. In addition to this, the absence of spatial inhomogeneities is reflected as disappearance of nondecay component in the intermediate dynamic structure factor. Through the combination analysis of DLS and NSE, the multiscale dynamics of gels is elucidated. |
536 | _ | _ | |0 G:(DE-HGF)POF2-451 |a 451 - Soft Matter Composites (POF2-451) |c POF2-451 |f POF II |x 0 |
536 | _ | _ | |0 G:(DE-HGF)POF2-54G24 |a 54G - JCNS (POF2-54G24) |c POF2-54G24 |f POF II |x 1 |
588 | _ | _ | |a Dataset connected to CrossRef, juser.fz-juelich.de |
700 | 1 | _ | |0 P:(DE-Juel1)130872 |a Ohl, Michael |b 1 |u fzj |
700 | 1 | _ | |0 P:(DE-HGF)0 |a Sakai, Takamasa |b 2 |
700 | 1 | _ | |0 P:(DE-HGF)0 |a Shibayama, Mitsuhiro |b 3 |
773 | _ | _ | |0 PERI:(DE-600)1491942-4 |a 10.1021/ma402439v |g Vol. 47, no. 2, p. 763 - 770 |n 2 |p 763 - 770 |t Macromolecules |v 47 |x 1520-5835 |y 2014 |
856 | 4 | _ | |u https://juser.fz-juelich.de/record/187549/files/FZJ-2015-01178.pdf |y Restricted |
909 | C | O | |o oai:juser.fz-juelich.de:187549 |p VDB |
910 | 1 | _ | |0 I:(DE-588b)5008462-8 |6 P:(DE-Juel1)130872 |a Forschungszentrum Jülich GmbH |b 1 |k FZJ |
913 | 2 | _ | |0 G:(DE-HGF)POF3-623 |1 G:(DE-HGF)POF3-620 |2 G:(DE-HGF)POF3-600 |9 G:(DE-HGF)POF3-6G4 |a DE-HGF |b Forschungsbereich Materie |l Von Materie zu Materialien und Leben |v Facility topic: Neutrons for Research on Condensed Matter |x 0 |
913 | 2 | _ | |0 G:(DE-HGF)POF3-551 |1 G:(DE-HGF)POF3-550 |2 G:(DE-HGF)POF3-500 |a DE-HGF |b Key Technologies |l BioSoft – Fundamentals for future Technologies in the fields of Soft Matter and Life Sciences |v Functional Macromolecules and Complexes |x 1 |
913 | 2 | _ | |0 G:(DE-HGF)POF3-621 |1 G:(DE-HGF)POF3-620 |2 G:(DE-HGF)POF3-600 |9 G:(DE-HGF)POF3-6215 |a DE-HGF |b Forschungsbereich Materie |l Von Materie zu Materialien und Leben |v In-house research on the structure, dynamics and function of matter |x 2 |
913 | 1 | _ | |0 G:(DE-HGF)POF2-451 |1 G:(DE-HGF)POF2-450 |2 G:(DE-HGF)POF2-400 |a DE-HGF |b Schlüsseltechnologien |v Soft Matter Composites |x 0 |4 G:(DE-HGF)POF |3 G:(DE-HGF)POF2 |l BioSoft |
913 | 1 | _ | |0 G:(DE-HGF)POF2-54G24 |1 G:(DE-HGF)POF2-540 |2 G:(DE-HGF)POF2-500 |a DE-HGF |b Struktur der Materie |v JCNS |x 1 |4 G:(DE-HGF)POF |3 G:(DE-HGF)POF2 |l Forschung mit Photonen, Neutronen, Ionen |
914 | 1 | _ | |y 2014 |
915 | _ | _ | |0 StatID:(DE-HGF)0100 |2 StatID |a JCR |
915 | _ | _ | |0 StatID:(DE-HGF)0110 |2 StatID |a WoS |b Science Citation Index |
915 | _ | _ | |0 StatID:(DE-HGF)0111 |2 StatID |a WoS |b Science Citation Index Expanded |
915 | _ | _ | |0 StatID:(DE-HGF)0150 |2 StatID |a DBCoverage |b Web of Science Core Collection |
915 | _ | _ | |0 StatID:(DE-HGF)0199 |2 StatID |a DBCoverage |b Thomson Reuters Master Journal List |
915 | _ | _ | |0 StatID:(DE-HGF)0200 |2 StatID |a DBCoverage |b SCOPUS |
915 | _ | _ | |0 StatID:(DE-HGF)0300 |2 StatID |a DBCoverage |b Medline |
915 | _ | _ | |0 StatID:(DE-HGF)0310 |2 StatID |a DBCoverage |b NCBI Molecular Biology Database |
915 | _ | _ | |0 StatID:(DE-HGF)0420 |2 StatID |a Nationallizenz |
915 | _ | _ | |0 StatID:(DE-HGF)1150 |2 StatID |a DBCoverage |b Current Contents - Physical, Chemical and Earth Sciences |
915 | _ | _ | |0 StatID:(DE-HGF)9905 |2 StatID |a IF >= 5 |
920 | 1 | _ | |0 I:(DE-Juel1)ICS-1-20110106 |k ICS-1 |l Neutronenstreuung |x 0 |
920 | 1 | _ | |0 I:(DE-Juel1)JCNS-1-20110106 |k Neutronenstreuung ; JCNS-1 |l Neutronenstreuung |x 1 |
920 | 1 | _ | |0 I:(DE-Juel1)JCNS-SNS-20110128 |k JCNS-SNS |l JCNS-SNS |x 2 |
980 | _ | _ | |a journal |
980 | _ | _ | |a VDB |
980 | _ | _ | |a I:(DE-Juel1)ICS-1-20110106 |
980 | _ | _ | |a I:(DE-Juel1)JCNS-1-20110106 |
980 | _ | _ | |a I:(DE-Juel1)JCNS-SNS-20110128 |
980 | _ | _ | |a UNRESTRICTED |
981 | _ | _ | |a I:(DE-Juel1)IBI-8-20200312 |
981 | _ | _ | |a I:(DE-Juel1)JCNS-1-20110106 |
981 | _ | _ | |a I:(DE-Juel1)JCNS-1-20110106 |
981 | _ | _ | |a I:(DE-Juel1)JCNS-SNS-20110128 |
Library | Collection | CLSMajor | CLSMinor | Language | Author |
---|