000018761 001__ 18761
000018761 005__ 20240712100828.0
000018761 0247_ $$2DOI$$a10.5194/acp-12-1353-2012
000018761 0247_ $$2WOS$$aWOS:000300656500009
000018761 0247_ $$2Handle$$a2128/7372
000018761 0247_ $$2altmetric$$aaltmetric:3159624
000018761 037__ $$aPreJuSER-18761
000018761 041__ $$aeng
000018761 082__ $$a550
000018761 084__ $$2WoS$$aMeteorology & Atmospheric Sciences
000018761 1001_ $$0P:(DE-Juel1)VDB101669$$aSuminska-Ebersoldt, O.$$b0$$uFZJ
000018761 245__ $$aClOOCl photolysis at high solar zenith angles: analysis of the RECONCILE self-match flight
000018761 260__ $$aKatlenburg-Lindau$$bEGU$$c2012
000018761 300__ $$a1353 - 1365
000018761 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article
000018761 3367_ $$2DataCite$$aOutput Types/Journal article
000018761 3367_ $$00$$2EndNote$$aJournal Article
000018761 3367_ $$2BibTeX$$aARTICLE
000018761 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000018761 3367_ $$2DRIVER$$aarticle
000018761 440_0 $$09601$$aAtmospheric Chemistry and Physics$$v12$$x1680-7316$$y3
000018761 500__ $$aThe RECONCILE project is funded under the European Commission Seventh Framework Programme (FP7) under the Grant number RECONCILE-226365-FP7-ENV-2008-1. The Ph.D. student position of Olga Suminska-Ebersoldt is financed within the ENVIVAL-LIFE project through a grant from Bundesministerium fur Wirtschaft (BMWi) via DLR, Germany.
000018761 520__ $$aThe photolysis rate constant of dichlorine peroxide (ClOOCl, ClO dimer) J(ClOOCl) is a critical parameter in catalytic cycles destroying ozone (O-3) in the polar stratosphere. In the atmospherically relevant wavelength region (lambda > 310 nm), significant discrepancies between laboratory measurements of ClOOCl absorption cross sections and spectra cause a large uncertainty in J(ClOOCl). Previous investigations of the consistency of published JClOOCl with atmospheric observations of chlorine monoxide (ClO) and ClOOCl have focused on the photochemical equilibrium between ClOOCl formation and photolysis, and thus could only constrain the ratio of J(ClOOCl) over the ClOOCl formation rate constant k(rec). Here, we constrain the atmospherically effective J(ClOOCl) independent of k(rec), using ClO measured in the same air masses before and directly after sunrise during an aircraft flight that was part of the RECONCILE field campaign in the winter 2010 from Kiruna, Sweden. Over sunrise, when the ClO/ClOOCl system comes out of thermal equilibrium and the influence of the ClO recombination reaction is negligible, the increase in ClO concentrations is significantly faster than expected from J(ClOOCl) based on the absorption spectrum proposed by Pope et al. (2007), but does not warrant cross sections larger than recently published values by Papanastasiou et al. (2009). In particular, the existence of a significant ClOOCl absorption band longwards of 420 nm is not supported by our observations. The observed night-time ClO would not be consistent with a ClO/ClOOCl thermal equilibrium constant significantly higher than the one proposed by Plenge et al. (2005).
000018761 536__ $$0G:(DE-Juel1)FUEK491$$2G:(DE-HGF)$$aAtmosphäre und Klima (FUEK491)$$cFUEK491$$x0
000018761 536__ $$0G:(DE-Juel1)FUEK411$$2G:(DE-HGF)$$aScientific Computing (FUEK411)$$cFUEK411$$x1
000018761 536__ $$0G:(EU-Grant)226365$$aRECONCILE - Reconciliation of essential process parameters for an enhanced predictability of arctic stratospheric ozone loss and its climate interactions. (226365)$$c226365$$fFP7-ENV-2008-1$$x2
000018761 536__ $$0G:(DE-HGF)POF2-411$$a411 - Computational Science and Mathematical Methods (POF2-411)$$cPOF2-411$$fPOF II$$x3
000018761 588__ $$aDataset connected to Web of Science
000018761 650_7 $$2WoSType$$aJ
000018761 7001_ $$0P:(DE-HGF)0$$aLehmann, R.$$b1
000018761 7001_ $$0P:(DE-Juel1)VDB84893$$aWegner, T.$$b2$$uFZJ
000018761 7001_ $$0P:(DE-Juel1)129122$$aGrooß, J.-U.$$b3$$uFZJ
000018761 7001_ $$0P:(DE-HGF)0$$aHösen, E.$$b4
000018761 7001_ $$0P:(DE-HGF)0$$aWeigel, R.$$b5
000018761 7001_ $$0P:(DE-HGF)0$$aFrey, W.$$b6
000018761 7001_ $$0P:(DE-Juel1)129121$$aGriessbach, S.$$b7$$uFZJ
000018761 7001_ $$0P:(DE-HGF)0$$aMitev, V.$$b8
000018761 7001_ $$0P:(DE-HGF)0$$aEmde, C.$$b9
000018761 7001_ $$0P:(DE-HGF)0$$aVolk, C.  M.$$b10
000018761 7001_ $$0P:(DE-HGF)0$$aBorrmann, S.$$b11
000018761 7001_ $$0P:(DE-HGF)0$$aRex, M.$$b12
000018761 7001_ $$0P:(DE-Juel1)129158$$aStroh, F.$$b13$$uFZJ
000018761 7001_ $$0P:(DE-Juel1)VDB14301$$avon Hobe, M.$$b14$$uFZJ
000018761 773__ $$0PERI:(DE-600)2069847-1$$a10.5194/acp-12-1353-2012$$gVol. 12, p. 1353 - 1365$$p1353 - 1365$$q12<1353 - 1365$$tAtmospheric chemistry and physics$$v12$$x1680-7316$$y2012
000018761 8567_ $$uhttp://dx.doi.org/10.5194/acp-12-1353-2012
000018761 8564_ $$uhttps://juser.fz-juelich.de/record/18761/files/FZJ-18761.pdf$$yOpenAccess$$zPublished final document.
000018761 8564_ $$uhttps://juser.fz-juelich.de/record/18761/files/FZJ-18761.jpg?subformat=icon-1440$$xicon-1440$$yOpenAccess
000018761 8564_ $$uhttps://juser.fz-juelich.de/record/18761/files/FZJ-18761.jpg?subformat=icon-180$$xicon-180$$yOpenAccess
000018761 8564_ $$uhttps://juser.fz-juelich.de/record/18761/files/FZJ-18761.jpg?subformat=icon-640$$xicon-640$$yOpenAccess
000018761 909CO $$ooai:juser.fz-juelich.de:18761$$pdnbdelivery$$pec_fundedresources$$pVDB$$pdriver$$popen_access$$popenaire
000018761 9132_ $$0G:(DE-HGF)POF3-511$$1G:(DE-HGF)POF3-510$$2G:(DE-HGF)POF3-500$$aDE-HGF$$bKey Technologies$$lSupercomputing & Big Data $$vComputational Science and Mathematical Methods$$x0
000018761 9131_ $$0G:(DE-HGF)POF2-411$$1G:(DE-HGF)POF2-410$$2G:(DE-HGF)POF2-400$$3G:(DE-HGF)POF2$$4G:(DE-HGF)POF$$aDE-HGF$$bSchlüsseltechnologien$$lSupercomputing$$vComputational Science and Mathematical Methods$$x3
000018761 9141_ $$y2012
000018761 915__ $$0LIC:(DE-HGF)CCBY3$$2HGFVOC$$aCreative Commons Attribution CC BY 3.0
000018761 915__ $$0StatID:(DE-HGF)0010$$2StatID$$aJCR/ISI refereed
000018761 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR
000018761 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000018761 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000018761 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000018761 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000018761 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000018761 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000018761 915__ $$0StatID:(DE-HGF)0500$$2StatID$$aDBCoverage$$bDOAJ
000018761 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000018761 915__ $$0StatID:(DE-HGF)1020$$2StatID$$aDBCoverage$$bCurrent Contents - Social and Behavioral Sciences
000018761 9201_ $$0I:(DE-Juel1)IEK-7-20101013$$gIEK$$kIEK-7$$lStratosphäre$$x1
000018761 9201_ $$0I:(DE-Juel1)JSC-20090406$$gJSC$$kJSC$$lJülich Supercomputing Centre$$x0
000018761 970__ $$aVDB:(DE-Juel1)133464
000018761 9801_ $$aFullTexts
000018761 980__ $$aVDB
000018761 980__ $$aConvertedRecord
000018761 980__ $$ajournal
000018761 980__ $$aI:(DE-Juel1)IEK-7-20101013
000018761 980__ $$aI:(DE-Juel1)JSC-20090406
000018761 980__ $$aUNRESTRICTED
000018761 980__ $$aJUWEL
000018761 980__ $$aFullTexts
000018761 981__ $$aI:(DE-Juel1)ICE-4-20101013
000018761 981__ $$aI:(DE-Juel1)JSC-20090406