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@ARTICLE{Tappertzhofen:187623,
      author       = {Tappertzhofen, Stefan and Waser, R. and Valov, Ilia},
      title        = {{I}mpact of the {C}ounter-{E}lectrode {M}aterial on {R}edox
                      {P}rocesses in {R}esistive {S}witching {M}emories},
      journal      = {ChemElectroChem},
      volume       = {1},
      number       = {8},
      issn         = {2196-0216},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2015-01249},
      pages        = {1287 - 1292},
      year         = {2014},
      abstract     = {Cation-based resistive-switching memories rely on the
                      injection and drift of metal ions in nanoscale thin films.
                      In insulators that do not initially contain mobile cations,
                      such as SiO2, Ta2O5, and so forth, water redox reactions
                      occurring at the counter electrode (CE) were found to be
                      essential in enabling the dissolution of the active
                      electrode and to keep electroneutrality. In this study, we
                      report on the impact of the CE on redox processes prior to
                      resistive switching. Potentiodynamic measurements for
                      various electrode materials revealed that the catalytic
                      activity of the CE towards the water redox process
                      determines the concentration of dissolved ions within the
                      oxide and influences the rate of the total cell reaction.
                      This trend can be used as an indicator for the design of
                      both cation- and anion-conducting oxide-based
                      resistive-switching random-access memories.},
      cin          = {PGI-7},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-7-20110106},
      pnm          = {421 - Frontiers of charge based Electronics (POF2-421)},
      pid          = {G:(DE-HGF)POF2-421},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000340523300005},
      doi          = {10.1002/celc.201402106},
      url          = {https://juser.fz-juelich.de/record/187623},
}