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@ARTICLE{Mamontov:187636,
author = {Mamontov, E. and Zolnierczuk, P. and Ohl, M.},
title = {{N}anometer-sized dynamic entities in an aqueous system},
journal = {Physical chemistry, chemical physics},
volume = {17},
number = {6},
issn = {1463-9084},
address = {Cambridge},
publisher = {RSC Publ.},
reportid = {FZJ-2015-01262},
pages = {4466 - 4471},
year = {2015},
abstract = {Using neutron spin-echo and backscattering spectroscopy, we
have found that at low temperatures water molecules in an
aqueous solution engage in center-of-mass dynamics that are
different from both the main structural relaxations and the
well-known localized motions in the transient cages of the
nearest neighbor molecules. While the latter localized
motions are known to take place on the picosecond time scale
and Angstrom length scale, the slower motions that we have
observed are found on the nanosecond time scale and
nanometer length scale. They are associated with the slow
secondary relaxations, or excess wing dynamics, in
glass-forming liquids. Our approach, therefore, can be
applied to probe the characteristic length scale of the
dynamic entities associated with slow dynamics in
glass-forming liquids, which presently cannot be studied by
other experimental techniques.},
cin = {ICS-1 / Neutronenstreuung ; JCNS-1 / JCNS-SNS},
ddc = {540},
cid = {I:(DE-Juel1)ICS-1-20110106 / I:(DE-Juel1)JCNS-1-20110106 /
I:(DE-Juel1)JCNS-SNS-20110128},
pnm = {551 - Functional Macromolecules and Complexes (POF3-551) /
6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
/ 6215 - Soft Matter, Health and Life Sciences (POF3-621)},
pid = {G:(DE-HGF)POF3-551 / G:(DE-HGF)POF3-6G4 /
G:(DE-HGF)POF3-6215},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000349005900057},
pubmed = {pmid:25578558},
doi = {10.1039/C4CP05081A},
url = {https://juser.fz-juelich.de/record/187636},
}