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@ARTICLE{Mora:187677,
      author       = {Mora, Elsa and Bras, Ana and Pyckhout-Hintzen, Wim and
                      Diogo, Hermínio P. and Moura Ramos, Joaquim J.},
      title        = {{T}he segmental and chain relaxation modes in
                      high-cis-polyisoprene as studied by thermally stimulated
                      currents},
      journal      = {The journal of chemical physics},
      volume       = {142},
      number       = {4},
      issn         = {1089-7690},
      address      = {Melville, NY},
      publisher    = {American Institute of Physics},
      reportid     = {FZJ-2015-01303},
      pages        = {044903},
      year         = {2015},
      abstract     = {The technique of Thermally Stimulated Currents is used to
                      study the slow molecular mobility in a series of poly
                      (1,4-cis-isoprene) samples with different molecular weights,
                      Mw , and low polydispersity. The technique revealed a high
                      resolution power, particularly useful in the study of the
                      lower molecular weight samples where the chain and the
                      segmental relaxations strongly overlap. The dynamic
                      crossover that is reported for the normal mode by varying
                      the molecular weight is clearly revealed by the thermally
                      stimulated depolarization currents results through the
                      temperature location, TMn , of the normal mode peak, the
                      values of the relaxation time at TMn , τ(TMn ), and the
                      value of the fragility index of the normal mode, mn . The
                      kinetic features of the glass transition relaxation of
                      polyisoprene have also been determined.},
      cin          = {ICS-1 / Neutronenstreuung ; JCNS-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ICS-1-20110106 / I:(DE-Juel1)JCNS-1-20110106},
      pnm          = {6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
                      / 6215 - Soft Matter, Health and Life Sciences (POF3-621) /
                      551 - Functional Macromolecules and Complexes (POF3-551)},
      pid          = {G:(DE-HGF)POF3-6G4 / G:(DE-HGF)POF3-6215 /
                      G:(DE-HGF)POF3-551},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000349018100046},
      doi          = {10.1063/1.4906542},
      url          = {https://juser.fz-juelich.de/record/187677},
}