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@ARTICLE{Birkel:18811,
      author       = {Birkel, C. S. and Kieslich, G. and Bessas, D. and Claudio,
                      T. and Branscheid, R. and Kolb, U. and Panthöfer, M. and
                      Hermann, R. and Tremel, W.},
      title        = {{W}et chemical synthesis and a combined x-ray and
                      {M}össbauer study of the formation of {F}e{S}b2
                      nanoparticles},
      journal      = {Inorganic chemistry},
      volume       = {50},
      issn         = {0020-1669},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {PreJuSER-18811},
      pages        = {11807 - 11812},
      year         = {2011},
      note         = {The DFG priority program SPP1386 "Nanostructured
                      Thermoelectrics" is acknowledged for support of this study.
                      C.S.B. and G.K. are recipients of a fellowship from MATCOR,
                      the Graduate School of Excellence of the State of
                      Rhineland-Palatinate. G.K. is a recipient of a fellowship
                      from the Konrad Adenauer Stiftung. R. H. acknowledges
                      support for the Helmholtz-University Young Investigator
                      Group "Lattices Dynamics in Emerging Functional Materials".},
      abstract     = {Understanding how solids form is a challenging task, and
                      few strategies allow for elucidation of reaction pathways
                      that are useful for designing the synthesis of solids. Here,
                      we report a powerful solution-mediated approach for
                      formation of nanocrystals of the thermoelectrically
                      promising FeSb(2) that uses activated metal nanoparticles as
                      precursors. The small particle size of the reactants ensures
                      minimum diffusion paths, low activation barriers, and low
                      reaction temperatures, thereby eliminating solid-solid
                      diffusion as the rate-limiting step in conventional
                      bulk-scale solid-state synthesis. A time- and
                      temperature-dependent study of formation of nanoparticular
                      FeSb(2) by X-ray powder diffraction and iron-57 Mössbauer
                      spectroscopy showed the incipient formation of the binary
                      phase in the temperature range of 200-250 °C.},
      keywords     = {J (WoSType)},
      cin          = {PGI-4 / JCNS-2 / JARA-FIT},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-4-20110106 / I:(DE-Juel1)JCNS-2-20110106 /
                      $I:(DE-82)080009_20140620$},
      pnm          = {Grundlagen für zukünftige Informationstechnologien /
                      Großgeräte für die Forschung mit Photonen, Neutronen und
                      Ionen (PNI)},
      pid          = {G:(DE-Juel1)FUEK412 / G:(DE-Juel1)FUEK415},
      shelfmark    = {Chemistry, Inorganic $\&$ Nuclear},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:22004092},
      UT           = {WOS:000296830400064},
      doi          = {10.1021/ic201940r},
      url          = {https://juser.fz-juelich.de/record/18811},
}