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| Hauptseite > Publikationsdatenbank > Li diffusive behavior of garnet-type oxides studied by muon-spin relaxation and QENS > print |
| Hauptseite > Publikationsdatenbank > Li diffusive behavior of garnet-type oxides studied by muon-spin relaxation and QENS > print |
| 001 | 188360 | ||
| 005 | 20210129215159.0 | ||
| 024 | 7 | _ | |2 doi |a 10.1016/j.ssi.2013.10.014 |
| 024 | 7 | _ | |2 ISSN |a 0167-2738 |
| 024 | 7 | _ | |2 ISSN |a 1872-7689 |
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| 100 | 1 | _ | |0 P:(DE-HGF)0 |a Nozaki, Hiroshi |b 0 |e Corresponding Author |
| 245 | _ | _ | |a Li diffusive behavior of garnet-type oxides studied by muon-spin relaxation and QENS |
| 260 | _ | _ | |a Amsterdam [u.a.] |b Elsevier Science |c 2014 |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1426175035_7693 |2 PUB:(DE-HGF) |
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| 520 | _ | _ | |a A diffusive behavior of Li+ ion in a garnet-type oxide, Li5 + xLa3ZrxNb2 − x012 with x = 0–2, has been investigated by both a positive muon-spin relaxation (μ+SR) and quasi-elastic neutron scattering (QENS) technique using powder samples. The μ+SR results revealed that Li+ ions start to diffuse above ~ 150 K for the whole samples measured. The activation energy of Li diffusion (Ea) estimated from the μ+SR data was in good agreement with Ea obtained by the QENS measurements. However, both Eas were about a half of Ea of ionic conductivity of Li+ (σLi), which was evaluated by AC-impedance measurements on sintered pellets. This indicated the serious effect of grain boundary and/or surface on Ea. Furthermore, since the diffusion coefficient of Li+ estimated by μ+SR is roughly independent of x, the number of mobile Li+ in the garnet lattice was found to be the predominant parameter to determine σLi. |
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| 773 | _ | _ | |0 PERI:(DE-600)1500750-9 |a 10.1016/j.ssi.2013.10.014 |g Vol. 262, p. 585 - 588 |p 585 - 588 |t Solid state ionics |v 262 |x 0167-2738 |y 2014 |
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