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@ARTICLE{Du:188384,
      author       = {Du, Linnan and Mauer, Georg and Vassen, Robert},
      title        = {{R}eaction {B}ehavior of the {L}i-{N}-{H} {H}ydrogen
                      {S}torage {S}ystem with {B}oron {N}itride as an {A}dditive},
      journal      = {Metallurgical and materials transactions / E},
      volume       = {2},
      number       = {1},
      issn         = {2196-2936},
      address      = {New York, NY},
      publisher    = {Springer},
      reportid     = {FZJ-2015-01782},
      pages        = {50-57},
      year         = {2015},
      abstract     = {This work begins with a discussion of the desorption,
                      reaction rate-limiting step of a LiNH2-LiH hydrogen storage
                      system. Using microstructural and thermodynamic studies, it
                      explains the working mechanism of BN as an additive in
                      Li-N-H hydrogen storage materials. High-energy wet ball
                      milling with THF was applied to the LiNH2 + 1.2LiH mixture.
                      The results obtained in this work show that the
                      rate-limiting step of the desorption reaction depends on the
                      degree of oxidation and amount of LiH in the system. The
                      activation energy of the desorption reaction of both
                      ball-milled LiNH2 and LiNH2 + 1.2LiH samples was reduced
                      with BN as an additive. BN had no clear impact on the
                      crystallite sizes of LiNH2 + 1.2LiH as-milled samples.
                      However, it was found that BN stabilizes the crystallite
                      sizes of LiNH2 + 1.2LiH samples during the high-temperature
                      desorption and absorption processes.},
      cin          = {IEK-1},
      ddc          = {620},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {113 - Methods and Concepts for Material Development
                      (POF3-113)},
      pid          = {G:(DE-HGF)POF3-113},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000218513600007},
      doi          = {10.1007/s40553-015-0043-z},
      url          = {https://juser.fz-juelich.de/record/188384},
}