Home > Publications database > Reaction Behavior of the Li-N-H Hydrogen Storage System with Boron Nitride as an Additive > print |
001 | 188384 | ||
005 | 20240711085644.0 | ||
024 | 7 | _ | |a 10.1007/s40553-015-0043-z |2 doi |
024 | 7 | _ | |a WOS:000218513600007 |2 WOS |
037 | _ | _ | |a FZJ-2015-01782 |
082 | _ | _ | |a 620 |
100 | 1 | _ | |a Du, Linnan |0 P:(DE-Juel1)138169 |b 0 |u fzj |
245 | _ | _ | |a Reaction Behavior of the Li-N-H Hydrogen Storage System with Boron Nitride as an Additive |
260 | _ | _ | |a New York, NY |c 2015 |b Springer |
336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1426493545_12957 |2 PUB:(DE-HGF) |
336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
336 | 7 | _ | |a ARTICLE |2 BibTeX |
336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
336 | 7 | _ | |a article |2 DRIVER |
520 | _ | _ | |a This work begins with a discussion of the desorption, reaction rate-limiting step of a LiNH2-LiH hydrogen storage system. Using microstructural and thermodynamic studies, it explains the working mechanism of BN as an additive in Li-N-H hydrogen storage materials. High-energy wet ball milling with THF was applied to the LiNH2 + 1.2LiH mixture. The results obtained in this work show that the rate-limiting step of the desorption reaction depends on the degree of oxidation and amount of LiH in the system. The activation energy of the desorption reaction of both ball-milled LiNH2 and LiNH2 + 1.2LiH samples was reduced with BN as an additive. BN had no clear impact on the crystallite sizes of LiNH2 + 1.2LiH as-milled samples. However, it was found that BN stabilizes the crystallite sizes of LiNH2 + 1.2LiH samples during the high-temperature desorption and absorption processes. |
536 | _ | _ | |a 113 - Methods and Concepts for Material Development (POF3-113) |0 G:(DE-HGF)POF3-113 |c POF3-113 |x 0 |f POF III |
588 | _ | _ | |a Dataset connected to CrossRef, juser.fz-juelich.de |
700 | 1 | _ | |a Mauer, Georg |0 P:(DE-Juel1)129633 |b 1 |e Corresponding Author |u fzj |
700 | 1 | _ | |a Vassen, Robert |0 P:(DE-Juel1)129670 |b 2 |
773 | _ | _ | |a 10.1007/s40553-015-0043-z |0 PERI:(DE-600)2750815-8 |n 1 |p 50-57 |t Metallurgical and materials transactions / E |v 2 |y 2015 |x 2196-2936 |
856 | 4 | _ | |u https://juser.fz-juelich.de/record/188384/files/FZJ-2015-01782.pdf |y Restricted |
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910 | 1 | _ | |a Forschungszentrum Jülich GmbH |0 I:(DE-588b)5008462-8 |k FZJ |b 2 |6 P:(DE-Juel1)129670 |
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914 | 1 | _ | |y 2015 |
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