001     188384
005     20240711085644.0
024 7 _ |a 10.1007/s40553-015-0043-z
|2 doi
024 7 _ |a WOS:000218513600007
|2 WOS
037 _ _ |a FZJ-2015-01782
082 _ _ |a 620
100 1 _ |a Du, Linnan
|0 P:(DE-Juel1)138169
|b 0
|u fzj
245 _ _ |a Reaction Behavior of the Li-N-H Hydrogen Storage System with Boron Nitride as an Additive
260 _ _ |a New York, NY
|c 2015
|b Springer
336 7 _ |a Journal Article
|b journal
|m journal
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|s 1426493545_12957
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336 7 _ |a Output Types/Journal article
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336 7 _ |a Journal Article
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336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a article
|2 DRIVER
520 _ _ |a This work begins with a discussion of the desorption, reaction rate-limiting step of a LiNH2-LiH hydrogen storage system. Using microstructural and thermodynamic studies, it explains the working mechanism of BN as an additive in Li-N-H hydrogen storage materials. High-energy wet ball milling with THF was applied to the LiNH2 + 1.2LiH mixture. The results obtained in this work show that the rate-limiting step of the desorption reaction depends on the degree of oxidation and amount of LiH in the system. The activation energy of the desorption reaction of both ball-milled LiNH2 and LiNH2 + 1.2LiH samples was reduced with BN as an additive. BN had no clear impact on the crystallite sizes of LiNH2 + 1.2LiH as-milled samples. However, it was found that BN stabilizes the crystallite sizes of LiNH2 + 1.2LiH samples during the high-temperature desorption and absorption processes.
536 _ _ |a 113 - Methods and Concepts for Material Development (POF3-113)
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|f POF III
588 _ _ |a Dataset connected to CrossRef, juser.fz-juelich.de
700 1 _ |a Mauer, Georg
|0 P:(DE-Juel1)129633
|b 1
|e Corresponding Author
|u fzj
700 1 _ |a Vassen, Robert
|0 P:(DE-Juel1)129670
|b 2
773 _ _ |a 10.1007/s40553-015-0043-z
|0 PERI:(DE-600)2750815-8
|n 1
|p 50-57
|t Metallurgical and materials transactions / E
|v 2
|y 2015
|x 2196-2936
856 4 _ |u https://juser.fz-juelich.de/record/188384/files/FZJ-2015-01782.pdf
|y Restricted
909 C O |o oai:juser.fz-juelich.de:188384
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910 1 _ |a Forschungszentrum Jülich GmbH
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910 1 _ |a Forschungszentrum Jülich GmbH
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910 1 _ |a Forschungszentrum Jülich GmbH
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913 0 _ |a DE-HGF
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913 1 _ |a DE-HGF
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|v Methods and Concepts for Material Development
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914 1 _ |y 2015
915 _ _ |a Peer Review unknown
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920 1 _ |0 I:(DE-Juel1)IEK-1-20101013
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980 _ _ |a journal
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980 _ _ |a I:(DE-Juel1)IEK-1-20101013
980 _ _ |a UNRESTRICTED
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