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@ARTICLE{Goossen:188468,
author = {Goossen, Sebastian and Bras, Ana and Pyckhout-Hintzen, Wim
and Wischnewski, Andreas and Richter, Dieter and Rubinstein,
Michael and Roovers, Jacques and Lutz, Pierre J. and Jeong,
Youncheol and Chang, Taihyun and Vlassopoulos, Dimitris},
title = {{I}nfluence of the {S}olvent {Q}uality on {R}ing {P}olymer
{D}imensions},
journal = {Macromolecules},
volume = {48},
number = {5},
issn = {1520-5835},
address = {Washington, DC},
publisher = {Soc.},
reportid = {FZJ-2015-01843},
pages = {1598–1605},
year = {2015},
abstract = {We present a systematic investigation of
well-characterized, experimentally pure polystyrene (PS)
rings with molar mass of 161 000 g/mol in dilute
solutions. We measure the ring form factor at θ- and
good-solvent conditions as well as in a polymeric solvent
(linear PS of roughly comparable molar mass) by means of
small-angle neutron scattering (SANS). Additional dynamic
light scattering (DLS) measurements support the SANS data
and help elucidate the role of solvent quality and solution
preparation. The results indicate the increase of ring
dimensions as the solvent quality improves. Furthermore, the
experimental form factors in both θ-solvent and linear
matrix behave as ideal rings and are fully superimposable.
The nearly Gaussian conformations of rings in a melt of
linear chains provide evidence of threading of linear chains
through rings. The latter result has implications for the
dynamics of ring–linear polymer mixtures.},
cin = {ICS-1 / Neutronenstreuung ; JCNS-1},
ddc = {540},
cid = {I:(DE-Juel1)ICS-1-20110106 / I:(DE-Juel1)JCNS-1-20110106},
pnm = {551 - Functional Macromolecules and Complexes (POF3-551) /
6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
/ 6215 - Soft Matter, Health and Life Sciences (POF3-621)},
pid = {G:(DE-HGF)POF3-551 / G:(DE-HGF)POF3-6G4 /
G:(DE-HGF)POF3-6215},
experiment = {EXP:(DE-MLZ)KWS1-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000350918700040},
doi = {10.1021/ma502518p},
url = {https://juser.fz-juelich.de/record/188468},
}