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005     20221213131507.0
024 7 _ |a 10.1103/PhysRevLett.114.106804
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100 1 _ |a Sforzini, J.
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245 _ _ |a Approaching Truly Freestanding Graphene: The Structure of Hydrogen-Intercalated Graphene on 6H−SiC(0001)
260 _ _ |a College Park, Md.
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520 _ _ |a We measure the adsorption height of hydrogen-intercalated quasifreestanding monolayer graphene on the (0001) face of 6H silicon carbide by the normal incidence x-ray standing wave technique. A density functional calculation for the full (63√×63√)−R30° unit cell, based on a van der Waals corrected exchange correlation functional, finds a purely physisorptive adsorption height in excellent agreement with experiments, a very low buckling of the graphene layer, a very homogeneous electron density at the interface, and the lowest known adsorption energy per atom for graphene on any substrate. A structural comparison to other graphenes suggests that hydrogen-intercalated graphene on 6H−SiC(0001) approaches ideal graphene.
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700 1 _ |a Nemec, L.
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700 1 _ |a Denig, T.
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700 1 _ |a Stadtmüller, B.
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700 1 _ |a Lee, T.-L.
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700 1 _ |a Kumpf, C.
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700 1 _ |a Subach, Sergey
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700 1 _ |a Starke, U.
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700 1 _ |a Rinke, P.
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700 1 _ |a Blum, V.
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700 1 _ |a Posseik, Francois
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700 1 _ |a Tautz, Frank Stefan
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773 _ _ |a 10.1103/PhysRevLett.114.106804
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856 4 _ |u https://juser.fz-juelich.de/record/188581/files/FZJ-2015-01932.pdf
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