001     188655
005     20240619083508.0
024 7 _ |a 10.1039/c4sm00148f
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024 7 _ |a 1744-6848
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037 _ _ |a FZJ-2015-01987
041 _ _ |a English
082 _ _ |a 530
100 1 _ |a Lisicki, Maciej
|0 P:(DE-Juel1)157720
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|e Corresponding Author
245 _ _ |a Translational and rotational near-wall diffusion of spherical colloids studied by evanescent wave scattering
260 _ _ |a London
|c 2014
|b Royal Soc. of Chemistry
336 7 _ |a Journal Article
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336 7 _ |a article
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520 _ _ |a In this article we extend recent experimental developments [Rogers et al., Phys. Rev. Lett., 2012, 109, 098305] by providing a suitable theoretical framework for the derivation of exact expressions for the first cumulant (initial decay rate) of the correlation function measured in Evanescent Wave Dynamic Light Scattering (EWDLS) experiments. We focus on a dilute suspension of optically anisotropic spherical Brownian particles diffusing near a planar hard wall. In such a system, translational and rotational diffusion are hindered by hydrodynamic interactions with the boundary which reflects the flow incident upon it, affecting the motion of colloids. The validity of the approximation by the first cumulant for moderate times is assessed by juxtaposition to Brownian dynamics simulations, and compared with experimental results. The presented method for the analysis of experimental data allows the determination of penetration-depth-averaged rotational diffusion coefficients of spherical colloids at low density.
536 _ _ |a 451 - Soft Matter Composites (POF2-451)
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536 _ _ |a NANODIRECT - Toolbox for Directed and Controlled Self-Assembly of nano-Colloids (213948)
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700 1 _ |a Cichocki, Bogdan
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700 1 _ |a Rogers, Simon A.
|0 P:(DE-HGF)0
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700 1 _ |a Dhont, Jan K.G.
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700 1 _ |a Lang, Peter R.
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773 _ _ |a 10.1039/c4sm00148f
|g Vol. 10, no. 24, p. 4312 -
|0 PERI:(DE-600)2191476-X
|n 24
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|t Soft matter
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|y 2014
|x 1744-6848
856 4 _ |u https://juser.fz-juelich.de/record/188655/files/ewdls_soft_matter_paper_v3.pdf
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910 1 _ |a Forschungszentrum Jülich GmbH
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910 1 _ |a Forschungszentrum Jülich GmbH
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