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@INPROCEEDINGS{Wuttke:189036,
author = {Wuttke, Joachim and Bellissent-Funel, Marie-Claire and
Kaneko, Katsumi and Ohba, Tomonori and Appavou, Marie-Sousai
and Soininen, Antti},
title = {{T}he unimpressive origin of the apparent fragile-strong
transition.},
reportid = {FZJ-2015-02293},
year = {2015},
abstract = {Supercooled water is suspected to undergo a fragile-strong
transition (FST).Theoretical interest has been fostered by a
possible connection with a Widomline emanating from the
phase boundary between low and high densityamorphous ice.
Experimental support for the FST has mostly come from
high-resolution neutron spectroscopy. The FST appears as a
kink in the temperaturedependence of a mean relaxation time
<τ>. This interpretation depends criticallyon the
assumption that the experiment sees one and the same
relaxationprocess above and below the kink. Based on new
backscattering spectra ofwater in carbon nanohorns we show
that the contrary is the case.Formally, our fit function is
the same as regularly used in support of a FST: a sumof a
delta line, accounting for elastic scattering by the matrix,
and a Kohlrauschspectrum. This model suffers from parameter
degeneracies. Occam's razor tellsus to maximize constraints
under minimal physical assumptions. We useharmonic
extrapolations of the T dependent scattering intensity to
fix theamplitudes in our delta-plus-Kohlrausch fits. We then
identify two q,T regions thatadmit particularly stringent
constraints, and a crossover regime in between. Inthis way,
we find that quasielastic scattering reveals different
physics in differentq,T regimes: At low T, it is dominated
by localized motion; at high T by relaxation-coupled
diffusion.},
month = {Mar},
date = {2015-03-22},
organization = {XIV International Workshop on Complex
Systems., Fai della Paganella (Italy),
22 Mar 2015 - 25 Mar 2015},
subtyp = {Plenary/Keynote},
cin = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
(München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-1-20110106},
pnm = {6215 - Soft Matter, Health and Life Sciences (POF3-621) /
6G15 - FRM II / MLZ (POF3-6G15) / 6G4 - Jülich Centre for
Neutron Research (JCNS) (POF3-623)},
pid = {G:(DE-HGF)POF3-6215 / G:(DE-HGF)POF3-6G15 /
G:(DE-HGF)POF3-6G4},
experiment = {EXP:(DE-MLZ)SPHERES-20140101},
typ = {PUB:(DE-HGF)6},
url = {https://juser.fz-juelich.de/record/189036},
}