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@ARTICLE{Walsh:189120,
author = {Walsh, Zarah and Janeček, Emma-Rose and Hodgkinson, James
T. and Sedlmair, Julia and Koutsioumpas, Alexandros and
Spring, David R. and Welch, Martin and Hirschmugl, Carol J.
and Toprakcioglu, Chris and Nitschke, Jonathan R. and Jones,
Mark and Scherman, Oren A.},
title = {{M}ultifunctional supramolecular polymer networks as
next-generation consolidants for archaeological wood
conservation},
journal = {Proceedings of the National Academy of Sciences of the
United States of America},
volume = {111},
number = {50},
issn = {1091-6490},
address = {Washington, DC},
publisher = {National Acad. of Sciences},
reportid = {FZJ-2015-02333},
pages = {17743 - 17748},
year = {2014},
abstract = {The preservation of our cultural heritage is of great
importance to future generations. Despite this, significant
problems have arisen with the conservation of waterlogged
wooden artifacts. Three major issues facing conservators are
structural instability on drying, biological degradation,
and chemical degradation on account of Fe3+-catalyzed
production of sulfuric and oxalic acid in the waterlogged
timbers. Currently, no conservation treatment exists that
effectively addresses all three issues simultaneously. A new
conservation treatment is reported here based on a
supramolecular polymer network constructed from natural
polymers with dynamic cross-linking formed by a combination
of both host-guest complexation and a strong siderophore
pendant from a polymer backbone. Consequently, the proposed
consolidant has the ability to chelate and trap iron while
enhancing structural stability. The incorporation of
antibacterial moieties through a dynamic covalent linkage
into the network provides the material with improved
biological resistance. Exploiting an environmentally
compatible natural material with completely reversible
chemistries is a safer, greener alternative to current
strategies and may extend the lifetime of many culturally
relevant waterlogged artifacts around the world.},
cin = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
(München) ; JCNS-FRM-II},
ddc = {000},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218},
pnm = {54G - JCNS (POF2-54G24)},
pid = {G:(DE-HGF)POF2-54G24},
experiment = {EXP:(DE-MLZ)NOSPEC-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000346366500037},
pubmed = {pmid:25385610},
doi = {10.1073/pnas.1406037111},
url = {https://juser.fz-juelich.de/record/189120},
}