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@ARTICLE{Grzechnik:189246,
author = {Grzechnik, Andrzej and Comer, Sara and Kolis, Joseph W. and
Friese, Karen},
title = {{C}rystal structure and high-pressure stability of
hydrothermally grown {L}i{KT}m{F}$_{5}$},
journal = {Solid state sciences},
volume = {39},
issn = {1293-2558},
address = {Amsterdam [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2015-02434},
pages = {40 - 44},
year = {2015},
abstract = {Single crystals of LiKTmF5 were grown hydrothermally. Its
crystal structure was studied with single-crystal X-ray
diffraction to 8.6 GPa. The material is monoclinic (P21/c, Z
= 4) and does not undergo any phase transition in the
pressure range studied here. The analysis of its
pseudosymmetry with respect to the minimal k-supergroup C2/m
reveals that the deviations of the individual atoms from the
respective higher symmetrical positions in C2/m are
increasing on compression, i.e., due to the reduction of the
unit-cell volume. Such a behaviour is the opposite of the
effect of incorporation of various M cations in the LiKMF5
materials (M:Y and rare earths) at atmospheric conditions,
since LiKYbF5 and LiKLuF5 with the smallest unit cells
crystallize in space group C2/m, while LiLYF5 with a larger
unit cell has P21/c symmetry.},
cin = {JCNS-2 / PGI-4 / JARA-FIT},
ddc = {550},
cid = {I:(DE-Juel1)JCNS-2-20110106 / I:(DE-Juel1)PGI-4-20110106 /
$I:(DE-82)080009_20140620$},
pnm = {144 - Controlling Collective States (POF3-144) / 524 -
Controlling Collective States (POF3-524) / 6213 - Materials
and Processes for Energy and Transport Technologies
(POF3-621) / 6G4 - Jülich Centre for Neutron Research
(JCNS) (POF3-623)},
pid = {G:(DE-HGF)POF3-144 / G:(DE-HGF)POF3-524 /
G:(DE-HGF)POF3-6213 / G:(DE-HGF)POF3-6G4},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000348952700008},
doi = {10.1016/j.solidstatesciences.2014.11.002},
url = {https://juser.fz-juelich.de/record/189246},
}