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000189437 1001_ $$0P:(DE-HGF)0$$aPanchakarla, Leela S.$$b0
000189437 245__ $$aLanthanide-Based Functional Misfit-Layered Nanotubes
000189437 260__ $$aWeinheim$$bWiley-VCH$$c2014
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000189437 520__ $$aThe synthesis of nanotubes from layered compounds has generated substantial scientific interest. “Misfit” layered compounds (MLCs) of the general formula [(MX)1+x]m[TX2]n, where M can include Pb, Sb, rare earths; T=Cr, Nb, and X=S, Se can form layered structures, even though each sub-system alone is not necessarily a layered or a stable compound. A simple chemical method is used to synthesize these complex nanotubes from lanthanide-based misfit compounds. Quaternary nanotubular structures formed by partial substitution of the lanthanide atom in nanotubes by other elements are also confirmed. The driving force and mechanism of formation of these nanotubes is investigated by systematic temperature and time-dependent studies. A stress-inducement mechanism is proposed to explain the formation of the nanotubes. The resulting materials may find applications in fields that include thermoelectrics, light emitters, and catalysis and address fundamental physical issues in low dimensions.
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000189437 7001_ $$0P:(DE-HGF)0$$aPopovitz-Biro, Ronit$$b1
000189437 7001_ $$0P:(DE-Juel1)130723$$aHouben, Lothar$$b2$$ufzj
000189437 7001_ $$0P:(DE-Juel1)144121$$aDunin-Borkowski, Rafal$$b3$$ufzj
000189437 7001_ $$0P:(DE-HGF)0$$aTenne, Reshef$$b4$$eCorresponding Author
000189437 773__ $$0PERI:(DE-600)2011836-3$$a10.1002/anie.201404189$$gVol. 53, no. 27, p. 6920 - 6924$$n27$$p6920 - 6924$$tAngewandte Chemie / International edition$$v53$$x1433-7851$$y2014
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000189437 9132_ $$0G:(DE-HGF)POF3-143$$1G:(DE-HGF)POF3-140$$2G:(DE-HGF)POF3-100$$aDE-HGF$$bForschungsbereich Energie$$lFuture Information Technology - Fundamentals, Novel Concepts and Energy Efficiency (FIT)$$vControlling Configuration-Based Phenomena$$x0
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