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@ARTICLE{Panchakarla:189437,
author = {Panchakarla, Leela S. and Popovitz-Biro, Ronit and Houben,
Lothar and Dunin-Borkowski, Rafal and Tenne, Reshef},
title = {{L}anthanide-{B}ased {F}unctional {M}isfit-{L}ayered
{N}anotubes},
journal = {Angewandte Chemie / International edition},
volume = {53},
number = {27},
issn = {1433-7851},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2015-02604},
pages = {6920 - 6924},
year = {2014},
abstract = {The synthesis of nanotubes from layered compounds has
generated substantial scientific interest. “Misfit”
layered compounds (MLCs) of the general formula
[(MX)1+x]m[TX2]n, where M can include Pb, Sb, rare earths;
T=Cr, Nb, and X=S, Se can form layered structures, even
though each sub-system alone is not necessarily a layered or
a stable compound. A simple chemical method is used to
synthesize these complex nanotubes from lanthanide-based
misfit compounds. Quaternary nanotubular structures formed
by partial substitution of the lanthanide atom in nanotubes
by other elements are also confirmed. The driving force and
mechanism of formation of these nanotubes is investigated by
systematic temperature and time-dependent studies. A
stress-inducement mechanism is proposed to explain the
formation of the nanotubes. The resulting materials may find
applications in fields that include thermoelectrics, light
emitters, and catalysis and address fundamental physical
issues in low dimensions.},
cin = {PGI-5},
ddc = {540},
cid = {I:(DE-Juel1)PGI-5-20110106},
pnm = {42G - Peter Grünberg-Centre (PG-C) (POF2-42G41)},
pid = {G:(DE-HGF)POF2-42G41},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000338023000012},
pubmed = {pmid:24898937},
doi = {10.1002/anie.201404189},
url = {https://juser.fz-juelich.de/record/189437},
}