guest ::
| Home > Publications database > High-Temperature Systems for a catalytic CO-Shift Membrane Reactor > print |
| Home > Publications database > High-Temperature Systems for a catalytic CO-Shift Membrane Reactor > print |
| 001 | 189590 | ||
| 005 | 20240709094316.0 | ||
| 037 | _ | _ | |a FZJ-2015-02728 |
| 041 | _ | _ | |a English |
| 100 | 1 | _ | |a van Holt, Désirée |0 P:(DE-Juel1)144939 |b 0 |e Corresponding author |
| 111 | 2 | _ | |a EuroMembrane 2015 |c Prague |d 2015-07-04 - 2015-07-10 |w Czech Republic |
| 245 | _ | _ | |a High-Temperature Systems for a catalytic CO-Shift Membrane Reactor |
| 260 | _ | _ | |c 2015 |
| 336 | 7 | _ | |a Abstract |b abstract |m abstract |0 PUB:(DE-HGF)1 |s 1468331144_14482 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a Conference Paper |0 33 |2 EndNote |
| 336 | 7 | _ | |a INPROCEEDINGS |2 BibTeX |
| 336 | 7 | _ | |a conferenceObject |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Conference Abstract |2 DataCite |
| 336 | 7 | _ | |a OTHER |2 ORCID |
| 520 | _ | _ | |a High-Temperature Systems for a catalytic CO-Shift MembraneReactorDésirée van Holt, Emanuel Forster , Wilhelm A. Meulenberg, Michael Müller, Mariya E.Ivanova, Stefan Baumann, Robert VaßenForschungszentrum Jülich, Institute of Energy and Climate Research, Leo-Brandt-Str., D-52425Juelich, Germanycorresponding author: d.van.holt@fz-juelich.deThe sequestration of CO2 via H2-selective, ceramic membranes in an IGCC-power plantis a highly interesting method, particularly for the high-temperature range of600 °C − 900 °C, due to the low efficiency losses that can be reached. It was shown thateven for this high-temperature range the utilization of a CO-shift catalyst leads to aconsiderable increase of the CO-conversion, at least up to 900 °C compared to anoperation mode without catalyst[1]. However, the harsh conditions of an IGCC-powerplant lead to very challenging operation conditions for the dense H2-selectivemembranes as well as for the CO-shift-catalysts.The present work aimed at the development of thermo-chemically and microstructurallystable, active and compatible membrane-catalyst systems for futurecatalytic CO-shift membrane-reactors. Therefore, the ceramic mixed protonic electronicconductors BaCe0.2Zr0.7Yb0.08Ni0.02O3−d and La5.5WO12−d were combined with ironbased catalysts like Fe/Cr/Cu-spinels. These materials were already studied intensivelyregarding the planned applications and show very good properties [2]. Additionally, formembrane-catalyst systems it is strongly required that the combined components donot influence each other negatively i.e. by diffusion or reaction.Figure: SEM picture of a cross section through a membrane-catalyst system of a 86Fe14Cr-catalyst on atape cast supported La5.5WO12−d-membrane after operation in a membrane reactor at 850 °C.The investigation identified material combinations that seem to be highly applicablefor future catalytic CO-shift membrane reactors in the high-temperature range up to900 °C. As shown in the figure above, the 86Fe14Cr-spinel catalyst and the La5.5WO12−d-membrane show very good compatibility. Additional investigations on membranereactorperformance, long term stability and scale up are necessary.[1] D. van Holt, Keramische Membranen für die H2-Abtrennung in CO-Shift-Reaktoren, DissertationRuhr-Universität Bochum 2014.[2] D. van Holt, E. Forster, M.E. Ivanova, W.A. Meulenberg, M. Müller, S. Baumann, R. Vaßen, Ceramicmaterials for H2 transport membranes applicable for gas separation under coal-gasification-relatedconditions, J. Eur. Ceram. Soc. 34 (2014) 2381 – 2389. |
| 536 | _ | _ | |a 113 - Methods and Concepts for Material Development (POF3-113) |0 G:(DE-HGF)POF3-113 |c POF3-113 |f POF III |x 0 |
| 536 | _ | _ | |0 G:(DE-Juel1)HITEC-20170406 |x 1 |c HITEC-20170406 |a HITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406) |
| 700 | 1 | _ | |a Forster, Emanuel |0 P:(DE-Juel1)145588 |b 1 |
| 700 | 1 | _ | |a Meulenberg, Wilhelm Albert |0 P:(DE-Juel1)129637 |b 2 |
| 700 | 1 | _ | |a Müller, Michael |0 P:(DE-Juel1)129765 |b 3 |
| 700 | 1 | _ | |a Ivanova, Mariya |0 P:(DE-Juel1)129617 |b 4 |
| 700 | 1 | _ | |a Baumann, Stefan |0 P:(DE-Juel1)129587 |b 5 |
| 700 | 1 | _ | |a Vassen, Robert |0 P:(DE-Juel1)129670 |b 6 |u fzj |
| 773 | _ | _ | |y 2015 |
| 909 | C | O | |o oai:juser.fz-juelich.de:189590 |p VDB |
| 910 | 1 | _ | |a Forschungszentrum Jülich GmbH |0 I:(DE-588b)5008462-8 |k FZJ |b 0 |6 P:(DE-Juel1)144939 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 1 |6 P:(DE-Juel1)145588 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 2 |6 P:(DE-Juel1)129637 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 3 |6 P:(DE-Juel1)129765 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 4 |6 P:(DE-Juel1)129617 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 5 |6 P:(DE-Juel1)129587 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 6 |6 P:(DE-Juel1)129670 |
| 913 | 1 | _ | |a DE-HGF |l Energieeffizienz, Materialien und Ressourcen |1 G:(DE-HGF)POF3-110 |0 G:(DE-HGF)POF3-113 |2 G:(DE-HGF)POF3-100 |v Methods and Concepts for Material Development |x 0 |4 G:(DE-HGF)POF |3 G:(DE-HGF)POF3 |b Energie |
| 914 | 1 | _ | |y 2016 |
| 920 | _ | _ | |l yes |
| 920 | 1 | _ | |0 I:(DE-Juel1)IEK-9-20110218 |k IEK-9 |l Grundlagen der Elektrochemie |x 0 |
| 920 | 1 | _ | |0 I:(DE-Juel1)IEK-1-20101013 |k IEK-1 |l Werkstoffsynthese und Herstellungsverfahren |x 1 |
| 920 | 1 | _ | |0 I:(DE-Juel1)IEK-2-20101013 |k IEK-2 |l Werkstoffstruktur und -eigenschaften |x 2 |
| 980 | _ | _ | |a abstract |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a I:(DE-Juel1)IEK-9-20110218 |
| 980 | _ | _ | |a I:(DE-Juel1)IEK-1-20101013 |
| 980 | _ | _ | |a I:(DE-Juel1)IEK-2-20101013 |
| 980 | _ | _ | |a UNRESTRICTED |
| 981 | _ | _ | |a I:(DE-Juel1)IMD-1-20101013 |
| 981 | _ | _ | |a I:(DE-Juel1)IET-1-20110218 |
| 981 | _ | _ | |a I:(DE-Juel1)IMD-2-20101013 |
| 981 | _ | _ | |a I:(DE-Juel1)IEK-1-20101013 |
| 981 | _ | _ | |a I:(DE-Juel1)IEK-2-20101013 |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|