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000189591 1001_ $$0P:(DE-HGF)0$$aKim, Chang Jong$$b0
000189591 245__ $$aPolymer Chain Conformation on Deuterated Polystyrene Nanoparticles Investigated by SANS
000189591 260__ $$aLondon [u.a.] Taylor & Francis$$bTaylor & Francis$$c2014
000189591 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1429770412_1056
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000189591 520__ $$aWe previously reported that grafted polystyrene (PS) chains on silica nanoparticles at a low grafting density show similar conformations to free PS chains in the same solvent, THF (diameter ˜50 nm, Colloid.poly.Sci. (2013), 291, 9, 2087–2099). As an extension of our previous study we choose an organic nanoparticle (deuterated polystyrene, dPS) instead of inorganic nanoparticle to see the impact of the substrate material on chain conformation. Additionally, a wider range of molecular weights were prepared to investigate the conformation feature of grafted PS chains more in detail. Small angle neutron scattering (SANS) experiments were performed to characterize PS grafted dPS particles in good solvent condition, with deuterated toluene and deuterated THF as solvent. To get insight into the conformation of the grafted PS layer we apply a scaling law describing the dimension of free PS polymer in good solvent condition to the obtained thickness of the grafted PS layer. We find an overall agreement with the scaling law where the thickness of the grafted PS layer is slightly larger than 2Rg of the free polymer chains in the respective solvent giving hint for semi dilute polymer brush (SDPB) situation. 
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000189591 65017 $$0V:(DE-MLZ)GC-1602-2016$$2V:(DE-HGF)$$aPolymers, Soft Nano Particles and  Proteins$$x2
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000189591 65017 $$0V:(DE-MLZ)GC-140$$2V:(DE-HGF)$$aSoft Matter, Macromolecules, Complex fluids, Biophysics $$x0
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000189591 7001_ $$0P:(DE-HGF)0$$aKraska, Martin$$b1$$eCorresponding Author
000189591 7001_ $$0P:(DE-HGF)0$$aMazurowski, Markus$$b2
000189591 7001_ $$0P:(DE-HGF)0$$aSondergeld, Katrin$$b3
000189591 7001_ $$0P:(DE-HGF)0$$aGallei, Markus$$b4
000189591 7001_ $$0P:(DE-HGF)0$$aRehahn, Matthias$$b5
000189591 7001_ $$0P:(DE-HGF)0$$aStühn, Bernd$$b6
000189591 773__ $$0PERI:(DE-600)2178402-4$$a10.1080/1539445X.2014.930047$$gVol. 12, no. sup1, p. S41 - S48$$nSup. 1$$pS41 - S48$$tSoft materials$$v12$$x1539-4468$$y2014
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