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@ARTICLE{Zinn:18975,
      author       = {Zinn, T. and Willner, L. and Lund, R. and Pipich, V. and
                      Richter, D.},
      title        = {{E}quilibrium exchange kinetics in n-alkyl-{PEO} polymeric
                      micelles: single exponential relaxation and chain length
                      dependence},
      journal      = {Soft matter},
      volume       = {8},
      issn         = {1744-683X},
      address      = {Cambridge},
      publisher    = {Royal Society of Chemistry (RSC)},
      reportid     = {PreJuSER-18975},
      pages        = {623 - 626},
      year         = {2012},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {In this communication we present first results on the chain
                      exchange kinetics of n-alkyl-PEO polymeric micelles by
                      time-resolved small angle neutron scattering. We found that
                      the rate strongly depends on the alkyl-chain length and that
                      the relaxation function almost perfectly follows the single
                      exponential decay predicted by theory. The key achievement
                      of this study is the experimental verification that core
                      block polydispersity accounts for the almost logarithmic
                      time decay in block copolymer micelles as recently suggested
                      by Choi et al. The results thus directly show that unimer
                      exchange is the main mechanism for molecular exchange in
                      block copolymer micelles.},
      keywords     = {J (WoSType)},
      cin          = {ICS-1 / JCNS-1},
      ddc          = {530},
      cid          = {I:(DE-Juel1)ICS-1-20110106 / I:(DE-Juel1)JCNS-1-20110106},
      pnm          = {BioSoft: Makromolekulare Systeme und biologische
                      Informationsverarbeitung / Großgeräte für die Forschung
                      mit Photonen, Neutronen und Ionen (PNI)},
      pid          = {G:(DE-Juel1)FUEK505 / G:(DE-Juel1)FUEK415},
      experiment   = {EXP:(DE-MLZ)KWS1-20140101 / EXP:(DE-MLZ)KWS2-20140101},
      shelfmark    = {Chemistry, Physical / Materials Science, Multidisciplinary
                      / Physics, Multidisciplinary / Polymer Science},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000301793700005},
      doi          = {10.1039/c1sm06809a},
      url          = {https://juser.fz-juelich.de/record/18975},
}