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@ARTICLE{Heil:190037,
      author       = {Heil, Jannis and Liu, Shurong and Vereecken, Harry and
                      Brüggemann, Nicolas},
      title        = {{A}biotic nitrous oxide production from hydroxylamine in
                      soils and their dependence on soil properties},
      journal      = {Soil biology $\&$ biochemistry},
      volume       = {84},
      issn         = {0038-0717},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2015-02996},
      pages        = {107 - 115},
      year         = {2015},
      abstract     = {Despite the fact that microbial nitrification and
                      denitrification are considered the major soil N2O emission
                      sources, especially from agricultural soils, several abiotic
                      reactions involving the nitrification intermediate
                      hydroxylamine (NH2OH) have been identified leading to N2O
                      emissions, but are being neglected in most current studies.
                      Here, we studied N2O formation from NH2OH in cropland,
                      grassland, and forest soils in laboratory incubation
                      experiments. Incubations were conducted with and without the
                      addition of NH2OH to non-sterile and sterile soil samples.
                      N2O evolution was quantified with gas chromatography and
                      further analyzed with online laser absorption spectroscopy.
                      Additionally, the isotopic signature of the produced N2O
                      (δ15N, δ18O, and 15N site preference) was analyzed with
                      isotope ratio mass spectrometry. While the forest soil
                      samples showed hardly any N2O evolution upon the addition of
                      NH2OH, immediate and very large formation of N2O was
                      observed in the cropland soil, also in sterilized samples.
                      Correlation analysis revealed soil parameters that might
                      explain the variability of NH2OH-induced N2O production to
                      be: soil pH, C/N ratio, and Mn content. Our results suggest
                      a coupled biotic–abiotic production of N2O during
                      nitrification, e.g. due to leakage of the nitrification
                      intermediate NH2OH with subsequent reaction with the soil
                      matrix.},
      cin          = {IBG-3},
      ddc          = {570},
      cid          = {I:(DE-Juel1)IBG-3-20101118},
      pnm          = {255 - Terrestrial Systems: From Observation to Prediction
                      (POF3-255) / 255 - Terrestrial Systems: From Observation to
                      Prediction (POF3-255)},
      pid          = {G:(DE-HGF)POF3-255 / G:(DE-HGF)POF3-255},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000353087600011},
      doi          = {10.1016/j.soilbio.2015.02.022},
      url          = {https://juser.fz-juelich.de/record/190037},
}