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@ARTICLE{Sofer:190038,
      author       = {Sofer, Zdeněk and Jankovský, Ondřej and Šimek, Petr and
                      Sedmidubský, David and Šturala, Jiří and Kosina, Jiří
                      and Mikšová, Romana and Macková, Anna and Mikulics,
                      Martin and Pumera, Martin},
      title        = {{I}nsight into the {M}echanism of the {T}hermal {R}eduction
                      of {G}raphite {O}xide: {D}euterium-{L}abeled {G}raphite
                      {O}xide {I}s the {K}ey},
      journal      = {ACS nano},
      volume       = {9},
      number       = {5},
      issn         = {1936-086X},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2015-02997},
      pages        = {5478–5485},
      year         = {2015},
      abstract     = {For the past decade, researchers have been trying to
                      understand the mechanism of the thermal reduction of
                      graphite oxide. Because deuterium is widely used as a marker
                      in various organic reactions, we wondered if
                      deuterium-labeled graphite oxide could be the key to fully
                      understand this mechanism. Graphite oxides were prepared by
                      the Hofmann, Hummers, Staudenmaier, and Brodie methods, and
                      a deuterium-labeled analogue was synthesized by the Hofmann
                      method. All graphite oxides were analyzed not only using the
                      traditional techniques but also by gas chromatographymass
                      spectrometry (GC-MS) during exfoliation in hydrogen and
                      nitrogen atmospheres. GC-MS enabled us to compare
                      differences between the chemical compositions of the organic
                      exfoliation products formed during the thermal reduction of
                      these graphite oxides. Nuclear analytical methods
                      (Rutherford backscattering spectroscopy, elastic recoil
                      detection analysis) were used to calculate the
                      concentrations of light elements, including the ratio of
                      hydrogen to deuterium. Combining all of these results we
                      were able to determine graphite oxide's thermal reduction
                      mechanism. Carbon dioxide, carbon monoxide, and water are
                      formed from the thermal reduction of graphite oxide. This
                      process is also accompanied by various radical reactions
                      that lead to the formation of a large amount of carcinogenic
                      volatile organic compounds, and this will have major safety
                      implications for the mass production of graphene.},
      cin          = {PGI-9 / JARA-FIT},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-9-20110106 / $I:(DE-82)080009_20140620$},
      pnm          = {521 - Controlling Electron Charge-Based Phenomena
                      (POF3-521)},
      pid          = {G:(DE-HGF)POF3-521},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000355383000085},
      doi          = {10.1021/acsnano.5b01463},
      url          = {https://juser.fz-juelich.de/record/190038},
}