000190046 001__ 190046 000190046 005__ 20240619083510.0 000190046 0247_ $$2doi$$a10.1039/C5SM00678C 000190046 0247_ $$2ISSN$$a1744-683X 000190046 0247_ $$2ISSN$$a1744-6848 000190046 0247_ $$2WOS$$aWOS:000354449100018 000190046 0247_ $$2altmetric$$aaltmetric:3826148 000190046 0247_ $$2pmid$$apmid:25921331 000190046 0247_ $$2Handle$$a2128/22851 000190046 037__ $$aFZJ-2015-03005 000190046 041__ $$aEnglish 000190046 082__ $$a530 000190046 1001_ $$0P:(DE-Juel1)157698$$aRoa, Rafael$$b0$$eCorresponding Author$$ufzj 000190046 245__ $$aUltrafiltration modeling of non-ionic microgels 000190046 260__ $$aLondon$$bRoyal Soc. of Chemistry$$c2015 000190046 3367_ $$2DRIVER$$aarticle 000190046 3367_ $$2DataCite$$aOutput Types/Journal article 000190046 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1568788407_18881 000190046 3367_ $$2BibTeX$$aARTICLE 000190046 3367_ $$2ORCID$$aJOURNAL_ARTICLE 000190046 3367_ $$00$$2EndNote$$aJournal Article 000190046 520__ $$aMembrane ultrafiltration (UF) is a pressure driven process allowing for the separation and enrichment of protein solutions and dispersions of nanosized microgel particles. The permeate flux and the near-membrane concentration-polarization (CP) layer in this process is determined by advective-diffusive dispersion transport and the interplay of applied and osmotic transmembrane pressure contributions. The UF performance is thus strongly dependent on the membrane properties, the hydrodynamic structure of the Brownian particles, their direct and hydrodynamic interactions, and the boundary conditions. We present a macroscopic description of cross-flow UF of non-ionic microgels modeled as solvent-permeable spheres. Our filtration model involves recently derived semi-analytic expressions for the concentration-dependent collective diffusion coefficient and viscosity of permeable particle dispersions [Riest et al., Soft Matter, 2015, 11, 2821]. These expressions have been well tested against computer simulation and experimental results. We analyze the CP layer properties and the permeate flux at different operating conditions and discuss various filtration process efficiency and cost indicators. Our results show that the proper specification of the concentration-dependent transport coefficients is important for reliable filtration process predictions. We also show that the solvent permeability of microgels is an essential ingredient to the UF modeling. 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