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@ARTICLE{Gatta:190048,
author = {Gatta, G. Diego and Adamo, Ilaria and Meven, Martin and
Lambruschi, Erica},
title = {{A} single-crystal neutron and {X}-ray diffraction study of
pezzottaite,
{C}s({B}e$_{2}${L}i){A}l$_{2}${S}i$_{6}${O}$_{18}$},
journal = {Physics and chemistry of minerals},
volume = {39},
number = {10},
issn = {1432-2021},
address = {Berlin},
publisher = {Springer},
reportid = {FZJ-2015-03007},
pages = {829 - 840},
year = {2012},
abstract = {The chemical composition and the crystal structure of
pezzottaite [ideal composition Cs(Be2Li) Al2Si6O18; space
group: R3c, a = 15.9615(6) A ° , c = 27.8568(9) A ° ] from
the type locality in Ambatovita (central Madagascar) were
investigated by electron microprobe analysis in wavelength
dispersive mode, thermo-gravimetric analysis,
Fourier-transform infrared spectroscopy, single-crystal
X-ray (at 298 K) and neutron (at 2.3 K) diffraction. The
average chemical formula of the sample of pezzottaite
resulted Cs1,Cs2(Cs0.565Rb0.027K0.017)R0.600
Na1,Na2(Na0.101Ca0.024)R0.125Be2.078Li0.922 Al1,Al2(Mg0.002
Mn0.002Fe0.003Al1.978)R1.985
Si1,Si2,Si3(Al0.056Si5.944)R6O18 0.27H2O. The (unpolarized)
IR spectrum over the region 3,800–600 cm-1 was collected
and a comparison with the absorption bands found in beryl
carried out. In particular, two-weak absorption bands
ascribable to the fundamental H2O stretching vibrations
(i.e. 3,591 and 3,545 cm-1) were observed, despite the
mineral being nominally anhydrous. The X-ray and neutron
structure refinements showed: (a) a non-significant presence
of aluminium, beryllium or lithium at the Si1, Si2 and Si3
sites, (b) the absence (at a significant level) of lithium
at the octahedral Al1, Al2 and Al3 sites and (c) a partial
lithium/beryllium disordering between tetrahedral Be and Li
sites.},
cin = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
(München) ; JCNS-FRM-II / JCNS-2},
ddc = {550},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-2-20110106},
pnm = {54G - JCNS (POF2-54G24)},
pid = {G:(DE-HGF)POF2-54G24},
experiment = {EXP:(DE-MLZ)HEIDI-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000310539600006},
doi = {10.1007/s00269-012-0539-3},
url = {https://juser.fz-juelich.de/record/190048},
}